TY - JOUR
T1 - Crystal structure of cis-Tetracarbonylbis(chloromercury)iron
AU - Raston, Colin L.
AU - White, Allan H.
AU - Wild, Stanley Bruce
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound has been determined by direct methods from X-ray diffraction data and refined by least squares to a residual of 0.071 for 2647 ‘observed’ reflections. Crystals are monoclinic, C2/c, a = 36.81(1), b = 11.181(2), c = 20.369(5) Å, β = 95.28(3)o, Z = 32. There are four independent molecules in the asymmetric unit, all with the cis disposition of ligands (<Fe-Hg), 2.498 Å, <Hg-Fe-Hg), 80.9o); in one of the molecules one of the carbonyl sites is occupied by a more substantial moiety, possibly a result of partial occupancy of HgCl as a result of disorder or decomposition.
AB - The crystal structure of the title compound has been determined by direct methods from X-ray diffraction data and refined by least squares to a residual of 0.071 for 2647 ‘observed’ reflections. Crystals are monoclinic, C2/c, a = 36.81(1), b = 11.181(2), c = 20.369(5) Å, β = 95.28(3)o, Z = 32. There are four independent molecules in the asymmetric unit, all with the cis disposition of ligands (<Fe-Hg), 2.498 Å, <Hg-Fe-Hg), 80.9o); in one of the molecules one of the carbonyl sites is occupied by a more substantial moiety, possibly a result of partial occupancy of HgCl as a result of disorder or decomposition.
UR - http://www.scopus.com/inward/record.url?scp=84971101897&partnerID=8YFLogxK
U2 - 10.1071/CH9761905
DO - 10.1071/CH9761905
M3 - Article
AN - SCOPUS:84971101897
VL - 29
SP - 1905
EP - 1911
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 9
ER -