Crystal structure of diammonium aquapentachloroferrate(III)

Brian N. Figgis; Colin L. Raston; Raj Pal Sharma; Allan H. White

doi:10.1071/CH9782717

Crystal structure of diammonium aquapentachloroferrate(III)

Brian N. Figgis, Colin L. Raston, Raj Pal Sharma, Allan H. White

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The crystal structure of the title compound, (NH₄)₂ [FeCl₅(H₂O)], has been redetermined by singlecrystal X-ray diffraction at 295 K and refined by full matrix least squares to a residual of 0·054 for 1662 ‘observed’ reflections. Crystals are orthorhombic, Pnma, a 13·706(2), b 9·924(1), c 7·024(l) Å, Z 4. Fe-O is 2·110(4) Å Fe-Cl range between 2·323(1) Å (trans to OH2) and 2·350(l)-2·390(l) Å (cis), the latter distances being very dependent upon hydrogen-bonded interactions with nearby species.

Original language	English
Pages (from-to)	2717-2720
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	31
Issue number	12
DOIs	https://doi.org/10.1071/CH9782717
Publication status	Published - 1978
Externally published	Yes

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title = "Crystal structure of diammonium aquapentachloroferrate(III)",

abstract = "The crystal structure of the title compound, (NH4)2 [FeCl5(H2O)], has been redetermined by singlecrystal X-ray diffraction at 295 K and refined by full matrix least squares to a residual of 0·054 for 1662 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, Pnma, a 13·706(2), b 9·924(1), c 7·024(l) {\AA}, Z 4. Fe-O is 2·110(4) {\AA} Fe-Cl range between 2·323(1) {\AA} (trans to OH2) and 2·350(l)-2·390(l) {\AA} (cis), the latter distances being very dependent upon hydrogen-bonded interactions with nearby species.",

author = "Figgis, {Brian N.} and Raston, {Colin L.} and Sharma, {Raj Pal} and White, {Allan H.}",

year = "1978",

doi = "10.1071/CH9782717",

language = "English",

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journal = "Australian Journal of Chemistry",

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T1 - Crystal structure of diammonium aquapentachloroferrate(III)

AU - Figgis, Brian N.

AU - Raston, Colin L.

AU - Sharma, Raj Pal

AU - White, Allan H.

PY - 1978

Y1 - 1978

N2 - The crystal structure of the title compound, (NH4)2 [FeCl5(H2O)], has been redetermined by singlecrystal X-ray diffraction at 295 K and refined by full matrix least squares to a residual of 0·054 for 1662 ‘observed’ reflections. Crystals are orthorhombic, Pnma, a 13·706(2), b 9·924(1), c 7·024(l) Å, Z 4. Fe-O is 2·110(4) Å Fe-Cl range between 2·323(1) Å (trans to OH2) and 2·350(l)-2·390(l) Å (cis), the latter distances being very dependent upon hydrogen-bonded interactions with nearby species.

AB - The crystal structure of the title compound, (NH4)2 [FeCl5(H2O)], has been redetermined by singlecrystal X-ray diffraction at 295 K and refined by full matrix least squares to a residual of 0·054 for 1662 ‘observed’ reflections. Crystals are orthorhombic, Pnma, a 13·706(2), b 9·924(1), c 7·024(l) Å, Z 4. Fe-O is 2·110(4) Å Fe-Cl range between 2·323(1) Å (trans to OH2) and 2·350(l)-2·390(l) Å (cis), the latter distances being very dependent upon hydrogen-bonded interactions with nearby species.

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

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ER -

Crystal structure of diammonium aquapentachloroferrate(III)

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