TY - JOUR
T1 - Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum
AU - Brotherton, Peter D.
AU - Raston, Colin L.
AU - White, Allan H.
AU - Wild, Stanley Bruce
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) Å, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) Å. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.
AB - The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) Å, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) Å. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.
UR - http://www.scopus.com/inward/record.url?scp=37049112556&partnerID=8YFLogxK
U2 - 10.1039/DT9760001193
DO - 10.1039/DT9760001193
M3 - Article
AN - SCOPUS:37049112556
SP - 1193
EP - 1195
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
SN - 1470-479X
IS - 13
ER -