Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum

Peter D. Brotherton; Colin L. Raston; Allan H. White; Stanley Bruce Wild

doi:10.1039/DT9760001193

Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum

Peter D. Brotherton, Colin L. Raston, Allan H. White, Stanley Bruce Wild

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) Å, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) Å. The η⁵-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.

Original language	English
Pages (from-to)	1193-1195
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/DT9760001193
Publication status	Published - 1976
Externally published	Yes

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title = "Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum",

abstract = "The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) {\AA}, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) {\AA}. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.",

author = "Brotherton, {Peter D.} and Raston, {Colin L.} and White, {Allan H.} and Wild, {Stanley Bruce}",

year = "1976",

doi = "10.1039/DT9760001193",

language = "English",

pages = "1193--1195",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

number = "13",

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T1 - Crystal structure of dicarbonyl-η-cyclopentadienyl[(3-dimethylarsino)propyl]molybdenum

AU - Brotherton, Peter D.

AU - Raston, Colin L.

AU - White, Allan H.

AU - Wild, Stanley Bruce

PY - 1976

Y1 - 1976

N2 - The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) Å, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) Å. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.

AB - The crystal structure of the title compound has been determined from X-ray diffractometer data by the heavy-atom method and refined by least squares to R 0.060 for 2 013 observed reflections. Crystals are orthorhombic, space group Pcab, a = 15.903(5), b = 13.297(2), c = 12.925(2) Å, Z = 8. Mo-As is 2.533(2), and the Mo-C(alkyl) 2.35(1) Å. The η5-cyclopentadienyl group occupies an apical position in the pseudo-square-pyramidal complex.

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U2 - 10.1039/DT9760001193

DO - 10.1039/DT9760001193

M3 - Article

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1470-479X

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