Crystal Structure of fac-Tris- (pentane-2, 3, 4-trione 3-oximato)cobalt(III)

Brian N. Figgis; Colin L. Raston; Raj Pal Sharma; Allan H. White

doi:10.1071/CH9782437

Crystal Structure of fac-Tris- (pentane-2, 3, 4-trione 3-oximato)cobalt(III)

Brian N. Figgis, Colin L. Raston, Raj Pal Sharma, Allan H. White

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The crystal structure of the title compound has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of O·058 for 2363 ‘observed’ reflections. Crystals are triclinic, P1, Z 4, a 15·517(8), b 11·772(7), c 11·282(7)ì a 112·10(4), β94-80(3), γ 90·60(4)°. 〈Co-N, 0〉) distances are 1 • 88 ₃ , 1-92 ₅ àrespectively, the disposition of the three bidentate ligands within each of the two independent molecules being fac.

Original language	English
Pages (from-to)	2437-2440a
Journal	Australian Journal of Chemistry
Volume	31
Issue number	11
DOIs	https://doi.org/10.1071/CH9782437
Publication status	Published - 1978
Externally published	Yes

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title = "Crystal Structure of fac-Tris- (pentane-2, 3, 4-trione 3-oximato)cobalt(III)",

abstract = " The crystal structure of the title compound has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of O·058 for 2363 {\textquoteleft}observed{\textquoteright} reflections. Crystals are triclinic, P1, Z 4, a 15·517(8), b 11·772(7), c 11·282(7){\`i} a 112·10(4), β94-80(3), γ 90·60(4)°. 〈Co-N, 0〉) distances are 1 • 88 3 , 1-92 5 {\`a}respectively, the disposition of the three bidentate ligands within each of the two independent molecules being fac.",

author = "Figgis, {Brian N.} and Raston, {Colin L.} and Sharma, {Raj Pal} and White, {Allan H.}",

year = "1978",

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AU - Figgis, Brian N.

AU - Raston, Colin L.

AU - Sharma, Raj Pal

AU - White, Allan H.

PY - 1978

Y1 - 1978

N2 - The crystal structure of the title compound has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of O·058 for 2363 ‘observed’ reflections. Crystals are triclinic, P1, Z 4, a 15·517(8), b 11·772(7), c 11·282(7)ì a 112·10(4), β94-80(3), γ 90·60(4)°. 〈Co-N, 0〉) distances are 1 • 88 3 , 1-92 5 àrespectively, the disposition of the three bidentate ligands within each of the two independent molecules being fac.

AB - The crystal structure of the title compound has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of O·058 for 2363 ‘observed’ reflections. Crystals are triclinic, P1, Z 4, a 15·517(8), b 11·772(7), c 11·282(7)ì a 112·10(4), β94-80(3), γ 90·60(4)°. 〈Co-N, 0〉) distances are 1 • 88 3 , 1-92 5 àrespectively, the disposition of the three bidentate ligands within each of the two independent molecules being fac.

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VL - 31

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 11

ER -

Crystal Structure of fac-Tris- (pentane-2, 3, 4-trione 3-oximato)cobalt(III)

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