TY - JOUR
T1 - Crystal structure of hexakis(hydroxylamine-N)nickel(II) sulphate
AU - Engelhardt, L. M.
AU - Newman, P. W.G.
AU - Raston, C. L.
AU - White, A. H.
PY - 1974
Y1 - 1974
N2 - The crystal structure of the title compound, [Ni(NH2OH)6] SO4, has been determined at 298 K by photographic methods; the structure was solved by the heavy atom method and refined by block diagonal least-squares procedures to a residual of 0.095 (1166 independent reflections). Crystal data: triclinic, P1, a 14.026(3), b 6.741(2), c 6.358(1) Å, α-98.35(2), β 79.57(1), γ 95.06(2)°, Z 2. In the two crystallographically independent centrosymmetric cations, the nickel atoms are octahedrally coordinated by the ligand nitrogen atoms, , 2.12 Å, , 1.44 Å. The Ni-N-O angles range from 110 to 117°. The sulphate geometry is normal and undistorted.
AB - The crystal structure of the title compound, [Ni(NH2OH)6] SO4, has been determined at 298 K by photographic methods; the structure was solved by the heavy atom method and refined by block diagonal least-squares procedures to a residual of 0.095 (1166 independent reflections). Crystal data: triclinic, P1, a 14.026(3), b 6.741(2), c 6.358(1) Å, α-98.35(2), β 79.57(1), γ 95.06(2)°, Z 2. In the two crystallographically independent centrosymmetric cations, the nickel atoms are octahedrally coordinated by the ligand nitrogen atoms, , 2.12 Å, , 1.44 Å. The Ni-N-O angles range from 110 to 117°. The sulphate geometry is normal and undistorted.
UR - http://www.scopus.com/inward/record.url?scp=84971086497&partnerID=8YFLogxK
U2 - 10.1071/CH9740503
DO - 10.1071/CH9740503
M3 - Article
AN - SCOPUS:84971086497
SN - 0004-9425
VL - 27
SP - 503
EP - 507
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 3
ER -