Crystal structure of methyl 8-Iodo-4,5,7-trimethoxy-2-naphthoate

Donald W. Cameron; Geoffrey I. Feutrill; Lind J.H. Lammerts van Bueren; Colin L. Raston; Allan H. White

doi:10.1071/CH9772313

Crystal structure of methyl 8-Iodo-4,5,7-trimethoxy-2-naphthoate

Donald W. Cameron, Geoffrey I. Feutrill, Lind J.H. Lammerts van Bueren, Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

The crystal structure of the title compound, C₁₅H₁₅IO₅, has been determined by single crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.04 (2210 ‘observed’ reflections). Crystals are monoclinic, P2₁/c, a 10.294(5), b 18.868(9), c 7.549(6) Å, β 90.29(5)°, Z 4. The molecular geometry apart from the iodine environment is as expected; the crystal packing is such that the iodine lies close to a symmetry-related neighbour at II 4.148(2) Å and may account for the observed facile elimination of iodine from the solid on heating to 120°C.

Original language	English
Pages (from-to)	2313-2317
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	30
Issue number	10
DOIs	https://doi.org/10.1071/CH9772313
Publication status	Published - 1977
Externally published	Yes

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Cameron, D. W., Feutrill, G. I., Lammerts van Bueren, L. J. H., Raston, C. L., & White, A. H. (1977). Crystal structure of methyl 8-Iodo-4,5,7-trimethoxy-2-naphthoate. Australian Journal of Chemistry, 30(10), 2313-2317. https://doi.org/10.1071/CH9772313

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title = "Crystal structure of methyl 8-Iodo-4,5,7-trimethoxy-2-naphthoate",

abstract = "The crystal structure of the title compound, C15H15IO5, has been determined by single crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.04 (2210 {\textquoteleft}observed{\textquoteright} reflections). Crystals are monoclinic, P21/c, a 10.294(5), b 18.868(9), c 7.549(6) {\AA}, β 90.29(5)°, Z 4. The molecular geometry apart from the iodine environment is as expected; the crystal packing is such that the iodine lies close to a symmetry-related neighbour at II 4.148(2) {\AA} and may account for the observed facile elimination of iodine from the solid on heating to 120°C.",

author = "Cameron, {Donald W.} and Feutrill, {Geoffrey I.} and {Lammerts van Bueren}, {Lind J.H.} and Raston, {Colin L.} and White, {Allan H.}",

year = "1977",

doi = "10.1071/CH9772313",

language = "English",

volume = "30",

pages = "2313--2317",

journal = "Australian Journal of Chemistry",

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T1 - Crystal structure of methyl 8-Iodo-4,5,7-trimethoxy-2-naphthoate

AU - Cameron, Donald W.

AU - Feutrill, Geoffrey I.

AU - Lammerts van Bueren, Lind J.H.

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1977

Y1 - 1977

N2 - The crystal structure of the title compound, C15H15IO5, has been determined by single crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.04 (2210 ‘observed’ reflections). Crystals are monoclinic, P21/c, a 10.294(5), b 18.868(9), c 7.549(6) Å, β 90.29(5)°, Z 4. The molecular geometry apart from the iodine environment is as expected; the crystal packing is such that the iodine lies close to a symmetry-related neighbour at II 4.148(2) Å and may account for the observed facile elimination of iodine from the solid on heating to 120°C.

AB - The crystal structure of the title compound, C15H15IO5, has been determined by single crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.04 (2210 ‘observed’ reflections). Crystals are monoclinic, P21/c, a 10.294(5), b 18.868(9), c 7.549(6) Å, β 90.29(5)°, Z 4. The molecular geometry apart from the iodine environment is as expected; the crystal packing is such that the iodine lies close to a symmetry-related neighbour at II 4.148(2) Å and may account for the observed facile elimination of iodine from the solid on heating to 120°C.

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