Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate

Terence M. Greaney; Colin L. Raston; Allan H. White; Edward N. Maslen

doi:10.1039/DT9750000876

Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate

Terence M. Greaney, Colin L. Raston, Allan H. White, Edward N. Maslen

Research output: Contribution to journal › Article

20 Citations (Scopus)

Abstract

The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P2₁/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) Å, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C₅H₇O₂)₃]^- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) Å, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) Å.

Original language	English
Pages (from-to)	876-879
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/DT9750000876
Publication status	Published - 1975
Externally published	Yes

Access to Document

10.1039/DT9750000876Licence: In Copyright

Link to publication in Scopus

Fingerprint Dive into the research topics of 'Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate'. Together they form a unique fingerprint.

Cite this

Greaney, T. M., Raston, C. L., White, A. H., & Maslen, E. N. (1975). Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate. Journal of the Chemical Society, Dalton Transactions, (10), 876-879. https://doi.org/10.1039/DT9750000876

@article{633936c432d54ddaa1c762bdde55ac40,

title = "Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate",

abstract = "The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P21/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) {\AA}, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C5H7O2)3]- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) {\AA}, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) {\AA}.",

author = "Greaney, {Terence M.} and Raston, {Colin L.} and White, {Allan H.} and Maslen, {Edward N.}",

year = "1975",

doi = "10.1039/DT9750000876",

language = "English",

pages = "876--879",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

number = "10",

}

TY - JOUR

T1 - Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate

AU - Greaney, Terence M.

AU - Raston, Colin L.

AU - White, Allan H.

AU - Maslen, Edward N.

PY - 1975

Y1 - 1975

N2 - The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P21/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) Å, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C5H7O2)3]- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) Å, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) Å.

AB - The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P21/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) Å, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C5H7O2)3]- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) Å, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) Å.

UR - http://www.scopus.com/inward/record.url?scp=37049142200&partnerID=8YFLogxK

U2 - 10.1039/DT9750000876

DO - 10.1039/DT9750000876

M3 - Article

AN - SCOPUS:37049142200

SP - 876

EP - 879

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1470-479X

IS - 10

ER -