TY - JOUR
T1 - Crystal structure of potassium tris(acetylacetonato)cadmate(II) monohydrate
AU - Greaney, Terence M.
AU - Raston, Colin L.
AU - White, Allan H.
AU - Maslen, Edward N.
PY - 1975
Y1 - 1975
N2 - The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P21/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) Å, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C5H7O2)3]- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) Å, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) Å.
AB - The crystal structure of the title compound has been determined from single-crystal X-ray diffractometer data by the heavy-atom method, and refined to R 0.071 (1997 observed reflections) by block-diagonal least-squares. Crystals are monoclinic, P21/a, a = 16.46(1), b = 14.051(6), c = 8.404(3) Å, β = 101.60(3)°, Z = 4. The structure is comprised of discrete potassium cations and [Cd(C5H7O2)3]- anions, in which the metal atom is co-ordinated by the three ligands. with Cd-O 2.247(7)-2.325(9) Å, in a very good approximation to trigonal prismatic stereochemistry. The potassium environment is comprised of five of the six ligand oxygen atoms and the water molecule, with K-O 2.622(11)-2.802(8) Å.
UR - http://www.scopus.com/inward/record.url?scp=37049142200&partnerID=8YFLogxK
U2 - 10.1039/DT9750000876
DO - 10.1039/DT9750000876
M3 - Article
AN - SCOPUS:37049142200
SN - 1472-7773
SP - 876
EP - 879
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 10
ER -