TY - JOUR
T1 - Crystal structure of sodium trans-bis(ethane-l, 2-diamine)- disulfitocobaltate(III) trihydrate
AU - Fallon, Gary D.
AU - Raston, Colin L.
AU - White, Allan H.
AU - Yandell, John K.
PY - 1980
Y1 - 1980
N2 - The crystal structure of the title compound, Na[Co(en)2(SO3)2], 3H2O, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·068 for 1890 ‘observed’ reflections. Crystals are monoclinic, P21/c, a 8·481(3), b 13·661(6), c 13·715(6) Å, β 106·91(3)°, Z 4. The asymmetric unit of the structure contains two independent anions, each located about a crystallographic centre of symmetry. <Co-S> is 2·267 Å, the longest Co-S distance so far reported in cobalt(III)/sulfite complexes.
AB - The crystal structure of the title compound, Na[Co(en)2(SO3)2], 3H2O, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·068 for 1890 ‘observed’ reflections. Crystals are monoclinic, P21/c, a 8·481(3), b 13·661(6), c 13·715(6) Å, β 106·91(3)°, Z 4. The asymmetric unit of the structure contains two independent anions, each located about a crystallographic centre of symmetry. <Co-S> is 2·267 Å, the longest Co-S distance so far reported in cobalt(III)/sulfite complexes.
UR - http://www.scopus.com/inward/record.url?scp=84970617445&partnerID=8YFLogxK
U2 - 10.1071/CH9800665
DO - 10.1071/CH9800665
M3 - Article
AN - SCOPUS:84970617445
VL - 33
SP - 665
EP - 670
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 3
ER -