TY - JOUR
T1 - Crystal structure of trans-amminebis(ethane-1, 2-diamine)sulfitocobalt(iii) perchlorate
AU - Raston, Colin L.
AU - White, Allan H.
AU - Yandell, John K.
PY - 1980
Y1 - 1980
N2 - The crystal structure of the title compound, trans-[Co(C2N2H8)2(NH3)(SO3)] ClO4, has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0·061 for 2989 ‘observed’ reflections. Crystals are monoclinic, P 21/n, a 6·863(3), b 14·713(6), c 13·279(8) Å, β 104·45(4)°, Z 4. Whereas the Co-S bond has the common value of 2-227(2) Å, Co-N is remarkably long, being 2·070(3) Å, this being ascribed to a structural trans effect.
AB - The crystal structure of the title compound, trans-[Co(C2N2H8)2(NH3)(SO3)] ClO4, has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0·061 for 2989 ‘observed’ reflections. Crystals are monoclinic, P 21/n, a 6·863(3), b 14·713(6), c 13·279(8) Å, β 104·45(4)°, Z 4. Whereas the Co-S bond has the common value of 2-227(2) Å, Co-N is remarkably long, being 2·070(3) Å, this being ascribed to a structural trans effect.
UR - http://www.scopus.com/inward/record.url?scp=84970546335&partnerID=8YFLogxK
U2 - 10.1071/CH9801123
DO - 10.1071/CH9801123
M3 - Article
AN - SCOPUS:84970546335
SN - 0004-9425
VL - 33
SP - 1123
EP - 1128
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 5
ER -