TY - JOUR
T1 - Crystal structure of trans-aquabis(ethylenediamine)sulphitocobalt(III) perchlorate monohydrate
AU - Maslen, Edward N.
AU - Raston, Colin L.
AU - White, Allan H.
AU - Yandell, John K.
PY - 1975
Y1 - 1975
N2 - The crystal structure of the title compound, previously reported as having one less molecule of water, has been determined from X-ray diffractometer data and refined by least squares to R 0.080 for 1455 observed reflections. Crystals are monoclinic, space group P21/n, a = 11.210(3), b = 13.626(2), c = 9.727(3) Å, β = 105.17(2)°, Z = 4. Interatomic distances are: mean Co-N 1.94, Co-S 2.181(3), Co-O 2.037(7), mean Cl-O 1.41, and mean S-O 1.46 Å. The Co-OH2 distance is long, presumably as a consequence of the trans-effect of the sulphite ligand.
AB - The crystal structure of the title compound, previously reported as having one less molecule of water, has been determined from X-ray diffractometer data and refined by least squares to R 0.080 for 1455 observed reflections. Crystals are monoclinic, space group P21/n, a = 11.210(3), b = 13.626(2), c = 9.727(3) Å, β = 105.17(2)°, Z = 4. Interatomic distances are: mean Co-N 1.94, Co-S 2.181(3), Co-O 2.037(7), mean Cl-O 1.41, and mean S-O 1.46 Å. The Co-OH2 distance is long, presumably as a consequence of the trans-effect of the sulphite ligand.
UR - http://www.scopus.com/inward/record.url?scp=37049130165&partnerID=8YFLogxK
U2 - 10.1039/DT9750000327
DO - 10.1039/DT9750000327
M3 - Article
AN - SCOPUS:37049130165
SP - 327
EP - 329
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
SN - 1470-479X
IS - 4
ER -