TY - JOUR
T1 - Crystal structure of trans-ch1orobis(ethane-1, 2-diamine)- sulfitocobalt(iii) monohydrate
AU - Raston, Colin L.
AU - White, Allan H.
AU - Yandell, John K.
PY - 1980
Y1 - 1980
N2 - The crystal structure of the title compound, [Co(en)2C1S03], H2O (en = ethane-1, 2-diamine), has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0·050 for 3252 ‘observed’ reflections. Crystals are monoc1inic, P21/c, a 9·862(4), b 15·897(8), c 16·936(7) Å, β 117·44(4)°, Z 8. The two independent molecules in the asymmetric unit are pseudosymmetrically related. is 2·204 Å, while is the 1ongest six-coordinate cobalt(m)-chloride distance observed, being 2·377Å.
AB - The crystal structure of the title compound, [Co(en)2C1S03], H2O (en = ethane-1, 2-diamine), has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0·050 for 3252 ‘observed’ reflections. Crystals are monoc1inic, P21/c, a 9·862(4), b 15·897(8), c 16·936(7) Å, β 117·44(4)°, Z 8. The two independent molecules in the asymmetric unit are pseudosymmetrically related. is 2·204 Å, while is the 1ongest six-coordinate cobalt(m)-chloride distance observed, being 2·377Å.
UR - http://www.scopus.com/inward/record.url?scp=84970550426&partnerID=8YFLogxK
U2 - 10.1071/CH9800419
DO - 10.1071/CH9800419
M3 - Article
AN - SCOPUS:84970550426
SN - 0004-9425
VL - 33
SP - 419
EP - 424
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 2
ER -