Crystal structure of tris (N, N-diethyldithiocarbamato) chromium(III)

Colin L. Raston; Allan H. White

doi:10.1071/CH9772091

Crystal structure of tris (N, N-diethyldithiocarbamato) chromium(III)

Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The crystal structure of the title compound [Cr(CS₂NEt₂)₃] has been determined at 295 K from X-ray diffractometer data and refined by least squares to a residual of 0.069 (3190 ‘observed’ reflections). Crystals are monoclinic, P2₁/n, a = 14.308(4), b = 10.389(4), c = 17.145(8) Å, β = 110.92(3)°, Z = 4, and are isostructural with the ruthenium and iron(III) (room temperature) analogues. <Cr-S> is 2.39₆ Å.

Original language	English
Pages (from-to)	2091-2094
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	30
Issue number	9
DOIs	https://doi.org/10.1071/CH9772091
Publication status	Published - 1977
Externally published	Yes

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title = "Crystal structure of tris (N, N-diethyldithiocarbamato) chromium(III)",

abstract = "The crystal structure of the title compound [Cr(CS2NEt2)3] has been determined at 295 K from X-ray diffractometer data and refined by least squares to a residual of 0.069 (3190 {\textquoteleft}observed{\textquoteright} reflections). Crystals are monoclinic, P21/n, a = 14.308(4), b = 10.389(4), c = 17.145(8) {\AA}, β = 110.92(3)°, Z = 4, and are isostructural with the ruthenium and iron(III) (room temperature) analogues. <Cr-S> is 2.396 {\AA}.",

author = "Raston, {Colin L.} and White, {Allan H.}",

year = "1977",

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T1 - Crystal structure of tris (N, N-diethyldithiocarbamato) chromium(III)

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1977

Y1 - 1977

N2 - The crystal structure of the title compound [Cr(CS2NEt2)3] has been determined at 295 K from X-ray diffractometer data and refined by least squares to a residual of 0.069 (3190 ‘observed’ reflections). Crystals are monoclinic, P21/n, a = 14.308(4), b = 10.389(4), c = 17.145(8) Å, β = 110.92(3)°, Z = 4, and are isostructural with the ruthenium and iron(III) (room temperature) analogues. <Cr-S> is 2.396 Å.

AB - The crystal structure of the title compound [Cr(CS2NEt2)3] has been determined at 295 K from X-ray diffractometer data and refined by least squares to a residual of 0.069 (3190 ‘observed’ reflections). Crystals are monoclinic, P21/n, a = 14.308(4), b = 10.389(4), c = 17.145(8) Å, β = 110.92(3)°, Z = 4, and are isostructural with the ruthenium and iron(III) (room temperature) analogues. <Cr-S> is 2.396 Å.

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DO - 10.1071/CH9772091

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 9

ER -

Crystal structure of tris (N, N-diethyldithiocarbamato) chromium(III)

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