Crystal structure of tris(diethyldithiocarbamato)iridium(III)

Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

23 Citations (Scopus)


The crystal structure of the title compound has been determined by the heavy-atom method from X-ray diffractometer data, and refined by full-matrix least-squares to R 0.064 for 3 292 observed reflections. Crystals are monoclinic, space group C2/c, and isostructural with the cobalt(III) analogue: a = 14.071(5), b = 10.477(3), c = 16.980(5) Å, β = 108.61 (2)°, Z = 4. Mean Ir-S is 2.367 Å.

Original languageEnglish
Pages (from-to)32-35
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number1
Publication statusPublished - 1976
Externally publishedYes


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