Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate

Colin L. Raston, Allan H. White, Anthony C. Willis

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Ni(en)3] (C1O4)2, H2O, has been determined from singlecrystal X-ray diffraction data at 295(1) K and refined by least squares to a residual of 0·093 for 1400 ‘observed’ reflections. Crystals are orthorhombic, Pbca, a 17·043(7), b 15·922(6), c 13·496(5) Å, Z 8. The precision of the structure determination is adversely affected by very high perchlorate thermal motion. <Ni-N> is 2·13 Å.

Original languageEnglish
Pages (from-to)415-418
Number of pages4
JournalAustralian Journal of Chemistry
Volume31
Issue number2
DOIs
Publication statusPublished - 1978
Externally publishedYes

Fingerprint Dive into the research topics of 'Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate'. Together they form a unique fingerprint.

Cite this