Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate

Colin L. Raston; Allan H. White; Anthony C. Willis

doi:10.1071/CH9780415

Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate

Colin L. Raston, Allan H. White, Anthony C. Willis

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Ni(en)₃] (C1O₄)₂, H₂O, has been determined from singlecrystal X-ray diffraction data at 295(1) K and refined by least squares to a residual of 0·093 for 1400 ‘observed’ reflections. Crystals are orthorhombic, Pbca, a 17·043(7), b 15·922(6), c 13·496(5) Å, Z 8. The precision of the structure determination is adversely affected by very high perchlorate thermal motion. <Ni-N> is 2·13 Å.

Original language	English
Pages (from-to)	415-418
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	31
Issue number	2
DOIs	https://doi.org/10.1071/CH9780415
Publication status	Published - 1978
Externally published	Yes

Access to Document

10.1071/CH9780415Licence: In Copyright

Cite this

@article{f420f42aa30849de83b7d64f400a641e,

title = "Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate",

abstract = "The crystal structure of the title compound, [Ni(en)3] (C1O4)2, H2O, has been determined from singlecrystal X-ray diffraction data at 295(1) K and refined by least squares to a residual of 0·093 for 1400 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, Pbca, a 17·043(7), b 15·922(6), c 13·496(5) {\AA}, Z 8. The precision of the structure determination is adversely affected by very high perchlorate thermal motion. is 2·13 {\AA}.",

author = "Raston, {Colin L.} and White, {Allan H.} and Willis, {Anthony C.}",

year = "1978",

doi = "10.1071/CH9780415",

language = "English",

volume = "31",

pages = "415--418",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "2",

}

TY - JOUR

T1 - Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate

AU - Raston, Colin L.

AU - White, Allan H.

AU - Willis, Anthony C.

PY - 1978

Y1 - 1978

N2 - The crystal structure of the title compound, [Ni(en)3] (C1O4)2, H2O, has been determined from singlecrystal X-ray diffraction data at 295(1) K and refined by least squares to a residual of 0·093 for 1400 ‘observed’ reflections. Crystals are orthorhombic, Pbca, a 17·043(7), b 15·922(6), c 13·496(5) Å, Z 8. The precision of the structure determination is adversely affected by very high perchlorate thermal motion. is 2·13 Å.

AB - The crystal structure of the title compound, [Ni(en)3] (C1O4)2, H2O, has been determined from singlecrystal X-ray diffraction data at 295(1) K and refined by least squares to a residual of 0·093 for 1400 ‘observed’ reflections. Crystals are orthorhombic, Pbca, a 17·043(7), b 15·922(6), c 13·496(5) Å, Z 8. The precision of the structure determination is adversely affected by very high perchlorate thermal motion. is 2·13 Å.

UR - http://www.scopus.com/inward/record.url?scp=84970541351&partnerID=8YFLogxK

U2 - 10.1071/CH9780415

DO - 10.1071/CH9780415

M3 - Article

AN - SCOPUS:84970541351

SN - 0004-9425

VL - 31

SP - 415

EP - 418

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 2

ER -

Crystal structure of Tris(ethane-1,2-diamine)nickel(II) diperchlorate monohydrate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this