Abstract
The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.
| Original language | English |
|---|---|
| Pages (from-to) | 1899-1904 |
| Number of pages | 6 |
| Journal | Australian Journal of Chemistry |
| Volume | 29 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1976 |
| Externally published | Yes |
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Mitra, S., Raston, C. L., & White, A. H. (1976). Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate. Australian Journal of Chemistry, 29(9), 1899-1904. https://doi.org/10.1071/CH9761899