TY - JOUR
T1 - Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate
AU - Mitra, Samaresh
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.
AB - The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.
UR - http://www.scopus.com/inward/record.url?scp=84971023724&partnerID=8YFLogxK
U2 - 10.1071/CH9761899
DO - 10.1071/CH9761899
M3 - Article
AN - SCOPUS:84971023724
VL - 29
SP - 1899
EP - 1904
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 9
ER -