Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate

Samaresh Mitra; Colin L. Raston; Allan H. White

doi:10.1071/CH9761899

Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate

Samaresh Mitra, Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Fe(CS₂NBu₂)₃], C₆H₆, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.

Original language	English
Pages (from-to)	1899-1904
Number of pages	6
Journal	Australian Journal of Chemistry
Volume	29
Issue number	9
DOIs	https://doi.org/10.1071/CH9761899
Publication status	Published - 1976
Externally published	Yes

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title = "Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate",

abstract = "The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) {\AA}. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, {\AA}. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.",

author = "Samaresh Mitra and Raston, {Colin L.} and White, {Allan H.}",

year = "1976",

doi = "10.1071/CH9761899",

language = "English",

volume = "29",

pages = "1899--1904",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "9",

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TY - JOUR

T1 - Crystal structure of Tris(N, N-dibutyldithiocarbamato)iron(III) benzene solvate

AU - Mitra, Samaresh

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1976

Y1 - 1976

N2 - The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.

AB - The crystal structure of the title compound, [Fe(CS2NBu2)3], C6H6, has been determined at 295 K from diffractometer data and refined by least squares to a residual of 0.071 for 3077 ‘observed’ reflections. Crystals are orthorhombic, Pncn, a = 23.660(9), b = 17.331(7), c = 10.349(9) Å. Unlike the unsolvated derivative, the present compound has a magnetic moment of 3.6 B.M. at 295 K. Its molecular symmetry is 2, (FeS) being 2.34, Å. The role of the benzene solvent, at a lattice site, is not indicative of any strong intermolecular interaction.

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