Crystal structure of tris(NN-diethyldithiocarbamato)iron(IV) pentaiodide

Colin L. Raston, Allan H. White, Dimitris Petridis, Donald Taylor

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

The crystal structure of the title compound [Fe(S2CNEt2)3][I5], has been determined by X-ray diffraction at 295(1) K, being refined to a residual of 0.049 for 3 328 'observed' reflections. Crystals are triclinic, space group P1, a = 17.41(1), b = 10.197(9), c = 10.184(8) Å, α = 74.71(6), β = 73.29(6), γ = 89.19(7)°, and Z = 2. The structure comprises [Fe(S2CNEt2)3]+ cations and I5- anions. Within the cation the symmetry is approximately D3 with six Fe-S distances ranging between 2.292(4) and 2.314(4) Å.

Original languageEnglish
Pages (from-to)1928-1931
Number of pages4
JournalJournal of the Chemical Society. Dalton Transactions
Issue number10
DOIs
Publication statusPublished - 1980
Externally publishedYes

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