TY - JOUR
T1 - Crystal structure of Tris(N,N-diethyldithiocarbamato)thallium(III)
AU - Kepert, David L.
AU - Raston, Colin L.
AU - Roberts, Nicholas K.
AU - Whitec, Allan H.
PY - 1978
Y1 - 1978
N2 - The crystal structure of the title compound, [Tl(S2CNEt2)3], has been determined by single-crystal X-ray diffraction methods at 295 K and refined by full-matrix least squares to a residual of 0·050 for 2517 ‘observed’ reflections. Crystals are monoclinic, with space group A2/a, a 14-789(7), b 10·428(4), c 18·207(9) Å, β 118·11(4)°, Z 4, and are isostructural with those of the previously determined gallium and indium analogues, the molecule having 2 symmetry with; T1-S> 2·666 Å. As in the dimethyl/thallium analogue, the departure of the TlS6 core symmetry from 3 is large and is examined in terms of electron-pair repulsion theory.
AB - The crystal structure of the title compound, [Tl(S2CNEt2)3], has been determined by single-crystal X-ray diffraction methods at 295 K and refined by full-matrix least squares to a residual of 0·050 for 2517 ‘observed’ reflections. Crystals are monoclinic, with space group A2/a, a 14-789(7), b 10·428(4), c 18·207(9) Å, β 118·11(4)°, Z 4, and are isostructural with those of the previously determined gallium and indium analogues, the molecule having 2 symmetry with; T1-S> 2·666 Å. As in the dimethyl/thallium analogue, the departure of the TlS6 core symmetry from 3 is large and is examined in terms of electron-pair repulsion theory.
UR - http://www.scopus.com/inward/record.url?scp=84970544547&partnerID=8YFLogxK
U2 - 10.1071/CH9781927
DO - 10.1071/CH9781927
M3 - Article
AN - SCOPUS:84970544547
SN - 0004-9425
VL - 31
SP - 1927
EP - 1932
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 9
ER -