TY - JOUR
T1 - Crystal Structure of Tris(pyridine- 2-carboxylato)manganese (in) Monohydrate
AU - Figgis, Brian N.
AU - Raston, Colin L.
AU - Sharma, Raj Pal
AU - White, Allan H.
PY - 1978/1/1
Y1 - 1978/1/1
N2 -
The crystal structure of the title compound, [Mn(C
5
H
4
NCO
2
)
3
], H
2
O, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0·053 for 2234 ‘observed’ reflections. Crystals are monoclinic, C2/c, a 30·50(2), b 8·387(8), c 13·903(7) ì β94·15(3)°, Z 8. The geometry of the manganese environment displays a pseudo-tetragonal distortion, the axial atoms being nitrogen (Mn-N 2·254(6), 2·217(6) é. The equatorial atoms are at distances Mn-N 2·059(5) ì Mn-0 1·891(5), 1·908(5), 1·942(5) ì the latter being trans to the nitrogen. The occupancy of the water molecule site is 0·54(1).
AB -
The crystal structure of the title compound, [Mn(C
5
H
4
NCO
2
)
3
], H
2
O, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0·053 for 2234 ‘observed’ reflections. Crystals are monoclinic, C2/c, a 30·50(2), b 8·387(8), c 13·903(7) ì β94·15(3)°, Z 8. The geometry of the manganese environment displays a pseudo-tetragonal distortion, the axial atoms being nitrogen (Mn-N 2·254(6), 2·217(6) é. The equatorial atoms are at distances Mn-N 2·059(5) ì Mn-0 1·891(5), 1·908(5), 1·942(5) ì the latter being trans to the nitrogen. The occupancy of the water molecule site is 0·54(1).
UR - http://www.scopus.com/inward/record.url?scp=0000467710&partnerID=8YFLogxK
U2 - 10.1071/CH9782545
DO - 10.1071/CH9782545
M3 - Article
AN - SCOPUS:0000467710
SN - 0004-9425
VL - 31
SP - 2545
EP - 2548
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 11
ER -