Abstract
The crystal structure of the title compound, [Fe(CS2N(CH2)4)3] (a new phase prepared from chloroform/toluene solutions), has been determined by single-crystal X-ray diffraction at 295 K and refined to a residual of 0•059 for 5651 ‘observed’ reflections. Crystals are monoclinic, P21/a, a 18•033(6), b 9•398(2), c 13•176(6) Å, β 100•80(3)°, Z 4. The compound is a purely high-spin derivative, the iron atom being in the usual pseudo-D3 environment with <Fe-S> very long (2-456Å).
Original language | English |
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Pages (from-to) | 547-553 |
Number of pages | 7 |
Journal | Australian Journal of Chemistry |
Volume | 31 |
Issue number | 3 |
DOIs | |
Publication status | Published - 1 Jan 1978 |
Externally published | Yes |