Crystal structure of Tris(pyrrolidine-1-carbodithioato)iron(III)

Samaresh Mitra, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)


The crystal structure of the title compound, [Fe(CS2N(CH2)4)3] (a new phase prepared from chloroform/toluene solutions), has been determined by single-crystal X-ray diffraction at 295 K and refined to a residual of 0•059 for 5651 ‘observed’ reflections. Crystals are monoclinic, P21/a, a 18•033(6), b 9•398(2), c 13•176(6) Å, β 100•80(3)°, Z 4. The compound is a purely high-spin derivative, the iron atom being in the usual pseudo-D3 environment with <Fe-S> very long (2-456Å).

Original languageEnglish
Pages (from-to)547-553
Number of pages7
JournalAustralian Journal of Chemistry
Issue number3
Publication statusPublished - 1 Jan 1978
Externally publishedYes


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