Cyclam as a supramolecular synthon: Infinite stacked arrays to encapsulation in superanions

Samantha Airey; Alexander Drljaca; Michaele J. Hardie; Colin L. Raston

doi:10.1039/a902124h

Cyclam as a supramolecular synthon: Infinite stacked arrays to encapsulation in superanions

Samantha Airey, Alexander Drljaca, Michaele J. Hardie, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Cyclam crystallised from CHCl₃-hexane gives infinite, hydrogen bonded assembled columns; in acidic aqueous media (pH 2) in the presence of sodium p-sulfonatocalix-[4]arene and the dichromium(III) aqua ion, the superanion or ionic capsule [[H₄(cyclam)]⁴⁺ proper subset {(p-sulfonatocalix[4]arene^4-)₂}]^4- crystallises as the salt of [Cr₂(OH)₂(H₂O)₈]⁴⁺.

Original language	English
Pages (from-to)	1137-1138
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/a902124h
Publication status	Published - 21 Jun 1999
Externally published	Yes

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title = "Cyclam as a supramolecular synthon: Infinite stacked arrays to encapsulation in superanions",

abstract = "Cyclam crystallised from CHCl3-hexane gives infinite, hydrogen bonded assembled columns; in acidic aqueous media (pH 2) in the presence of sodium p-sulfonatocalix-[4]arene and the dichromium(III) aqua ion, the superanion or ionic capsule [[H4(cyclam)]4+ proper subset {(p-sulfonatocalix[4]arene4-)2}]4- crystallises as the salt of [Cr2(OH)2(H2O)8]4+.",

author = "Samantha Airey and Alexander Drljaca and Hardie, {Michaele J.} and Raston, {Colin L.}",

year = "1999",

month = jun,

day = "21",

doi = "10.1039/a902124h",

language = "English",

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journal = "Chemical Communications",

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T1 - Cyclam as a supramolecular synthon

T2 - Infinite stacked arrays to encapsulation in superanions

AU - Airey, Samantha

AU - Drljaca, Alexander

AU - Hardie, Michaele J.

AU - Raston, Colin L.

PY - 1999/6/21

Y1 - 1999/6/21

N2 - Cyclam crystallised from CHCl3-hexane gives infinite, hydrogen bonded assembled columns; in acidic aqueous media (pH 2) in the presence of sodium p-sulfonatocalix-[4]arene and the dichromium(III) aqua ion, the superanion or ionic capsule [[H4(cyclam)]4+ proper subset {(p-sulfonatocalix[4]arene4-)2}]4- crystallises as the salt of [Cr2(OH)2(H2O)8]4+.

AB - Cyclam crystallised from CHCl3-hexane gives infinite, hydrogen bonded assembled columns; in acidic aqueous media (pH 2) in the presence of sodium p-sulfonatocalix-[4]arene and the dichromium(III) aqua ion, the superanion or ionic capsule [[H4(cyclam)]4+ proper subset {(p-sulfonatocalix[4]arene4-)2}]4- crystallises as the salt of [Cr2(OH)2(H2O)8]4+.

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U2 - 10.1039/a902124h

DO - 10.1039/a902124h

M3 - Article

AN - SCOPUS:0033591736

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SP - 1137

EP - 1138

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Cyclam as a supramolecular synthon: Infinite stacked arrays to encapsulation in superanions

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