Dichotomy of mechanism in the rearrangment of β-(acyloxy)alkyl radicals

Athelstan L.J. Beckwith; Peter J. Duggan

doi:10.1039/C39880001000

Dichotomy of mechanism in the rearrangment of β-(acyloxy)alkyl radicals

Athelstan L.J. Beckwith, Peter J. Duggan

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Differences between the rate constants and ¹⁸O distribution for the rearrangements of the β-(acyloxy)alkyl radicals (2b) and (7b) suggest that the first is a pericyclic reaction whereas the second proceeds through an anion-radical cation ion pair.

Original language	English
Pages (from-to)	1000-1002
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39880001000
Publication status	Published - 1988
Externally published	Yes

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title = "Dichotomy of mechanism in the rearrangment of β-(acyloxy)alkyl radicals",

abstract = "Differences between the rate constants and 18O distribution for the rearrangements of the β-(acyloxy)alkyl radicals (2b) and (7b) suggest that the first is a pericyclic reaction whereas the second proceeds through an anion-radical cation ion pair.",

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Dichotomy of mechanism in the rearrangment of β-(acyloxy)alkyl radicals

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