TY - JOUR
T1 - Differential cross sections for intermediate-energy electron scattering from α-tetrahydrofurfuryl alcohol
T2 - Excitation of electronic-states
AU - Chiari, Luca
AU - Vargas Duque, Humberto
AU - Jones, Darryl
AU - Thorn, Penny
AU - Pettifer, Zoe
AU - Barbosa Da Silva, George
AU - Limao-Vieira, P
AU - Duflot, D
AU - Hubin-Fraskin, M
AU - Delwiche, J
AU - Blanco, Francisco
AU - Garcia, Gustavo
AU - Lopes, M
AU - Ratnavelu, K
AU - White, Ronald
AU - Brunger, Michael
PY - 2014
Y1 - 2014
N2 - We report on measurements of differential cross sections (DCSs) for electron impact excitation of a series of Rydberg electronic-states in α-tetrahydrofurfuryl alcohol (THFA). The energy range of these experiments was 20-50 eV, while the scattered electron was detected in the 10°-90° angular range. There are currently no other experimental data or theoretical computations against which we can directly compare the present measured results. Nonetheless, we are able to compare our THFA DCSs with earlier cross section measurements for Rydberg-state electronic excitation for tetrahydrofuran, a similar cyclic ether, from Do et al. [J. Chem. Phys. 134, 144302 (2011)]. In addition, "rotationally averaged"elastic DCSs, calculated using our independent atom model with screened additivity rule correction approach are also reported. Those latter results give integral cross sections consistent with the optical theorem, and supercede those from the only previous study of Milosavljevićet al. [Eur. Phys. J. D 40, 107 (2006)].
AB - We report on measurements of differential cross sections (DCSs) for electron impact excitation of a series of Rydberg electronic-states in α-tetrahydrofurfuryl alcohol (THFA). The energy range of these experiments was 20-50 eV, while the scattered electron was detected in the 10°-90° angular range. There are currently no other experimental data or theoretical computations against which we can directly compare the present measured results. Nonetheless, we are able to compare our THFA DCSs with earlier cross section measurements for Rydberg-state electronic excitation for tetrahydrofuran, a similar cyclic ether, from Do et al. [J. Chem. Phys. 134, 144302 (2011)]. In addition, "rotationally averaged"elastic DCSs, calculated using our independent atom model with screened additivity rule correction approach are also reported. Those latter results give integral cross sections consistent with the optical theorem, and supercede those from the only previous study of Milosavljevićet al. [Eur. Phys. J. D 40, 107 (2006)].
UR - http://www.scopus.com/inward/record.url?scp=84904298863&partnerID=8YFLogxK
U2 - 10.1063/1.4885856
DO - 10.1063/1.4885856
M3 - Article
SN - 0021-9606
VL - 141
SP - 024301-1-024301-8
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 2
M1 - 024301
ER -