TY - JOUR
T1 - Direct measurement of methylene removal rates by species containing the OH functional group
AU - Staker, Warren S.
AU - King, Keith D.
AU - Gutsche, Greg J.
AU - Lawrance, Warren D.
PY - 1991
Y1 - 1991
N2 - The technique of laser flash photolysis/laser absorption has been used to obtain absolute removal rate constants for singlet methylene (1CH2) with N2, ketene (CH2CO), H2O, D2O, methanol (CH3OH), ethanol (C2H5OH), and n-propanol (n-C3H7OH) at 296 ± 2 K. The rate constants were found to be (0.130 ± 0.012), (2.38 ± 0.18), (1.60 ± 0.17), (1.05 ± 0.13), (2.20 ± 0.19), (2.61 ± 0.23) and (4.15 ± 0.44) × 10-10 cm3 molecule-1 s-1, respectively. The removal rate constants for the alcohols are consistently greater than those for the corresponding alkanes.
AB - The technique of laser flash photolysis/laser absorption has been used to obtain absolute removal rate constants for singlet methylene (1CH2) with N2, ketene (CH2CO), H2O, D2O, methanol (CH3OH), ethanol (C2H5OH), and n-propanol (n-C3H7OH) at 296 ± 2 K. The rate constants were found to be (0.130 ± 0.012), (2.38 ± 0.18), (1.60 ± 0.17), (1.05 ± 0.13), (2.20 ± 0.19), (2.61 ± 0.23) and (4.15 ± 0.44) × 10-10 cm3 molecule-1 s-1, respectively. The removal rate constants for the alcohols are consistently greater than those for the corresponding alkanes.
UR - http://www.scopus.com/inward/record.url?scp=0000689910&partnerID=8YFLogxK
U2 - 10.1039/FT9918702421
DO - 10.1039/FT9918702421
M3 - Article
AN - SCOPUS:0000689910
SN - 0956-5000
VL - 87
SP - 2421
EP - 2425
JO - Journal of the Chemical Society, Faraday Transactions
JF - Journal of the Chemical Society, Faraday Transactions
IS - 15
ER -