Abstract
Water-based nanoparticulate (NP) and bulk heterojunction (BHJ) organic photovoltaic (OPV) devices based on blends of poly(9,9-dioctylfluorene-co-N,N- bis(4-butylphenyl)-N,Ndiphenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-co-benzothiadiazole (F8BT) have been fabricated with aluminium and calcium/aluminium cathodes. The NP devices exhibit power conversion efficiencies (PCEs) that are double that of the corresponding BHJ device. Moreover, the addition of calcium into the cathode structure results in a dramatic increase in open circuit voltage and PCEs approaching 1 for water-based polyfluorene OPV devices.
Original language | English |
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Article number | 053901 |
Pages (from-to) | 053901 |
Number of pages | 4 |
Journal | Applied Physics Letters |
Volume | 101 |
Issue number | 5 |
DOIs | |
Publication status | Published - 30 Jul 2012 |