TY - JOUR
T1 - Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides
AU - Wang, Haipeng
AU - Pring, Allan
AU - Wu, Fei
AU - Chen, Guorong
AU - Jiang, Jianhua
AU - Xia, Fang
AU - Zhang, Jian
AU - Ngothai, Yung
AU - O'Neill, Brian
PY - 2006/6/1
Y1 - 2006/6/1
N2 - Iron monosulfides, Fe1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.
AB - Iron monosulfides, Fe1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.
KW - Iron monosulfide
KW - Nonstoichiometry
KW - Pyrrhotite
KW - Vacancy
UR - http://www.scopus.com/inward/record.url?scp=33645559311&partnerID=8YFLogxK
U2 - 10.1080/17415990600646124
DO - 10.1080/17415990600646124
M3 - Short survey
AN - SCOPUS:33645559311
VL - 27
SP - 271
EP - 282
JO - Journal of Sulfur Chemistry
JF - Journal of Sulfur Chemistry
SN - 1741-5993
IS - 3
ER -