Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides

Haipeng Wang; Allan Pring; Fei Wu; Guorong Chen; Jianhua Jiang; Fang Xia; Jian Zhang; Yung Ngothai; Brian O'Neill

doi:10.1080/17415990600646124

Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides

Haipeng Wang, Allan Pring, Fei Wu, Guorong Chen, Jianhua Jiang, Fang Xia, Jian Zhang, Yung Ngothai, Brian O'Neill

Research output: Contribution to journal › Short survey › peer-review

13 Citations (Scopus)

Abstract

Iron monosulfides, Fe_1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe_1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.

Original language	English
Pages (from-to)	271-282
Number of pages	12
Journal	Journal of Sulfur Chemistry
Volume	27
Issue number	3
DOIs	https://doi.org/10.1080/17415990600646124
Publication status	Published - 1 Jun 2006
Externally published	Yes

Keywords

Iron monosulfide
Nonstoichiometry
Pyrrhotite
Vacancy

Access to Document

10.1080/17415990600646124Licence: In Copyright

Cite this

@article{a251422266074b07a255a66ebebdb2dc,

title = "Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides",

abstract = "Iron monosulfides, Fe1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.",

keywords = "Iron monosulfide, Nonstoichiometry, Pyrrhotite, Vacancy",

author = "Haipeng Wang and Allan Pring and Fei Wu and Guorong Chen and Jianhua Jiang and Fang Xia and Jian Zhang and Yung Ngothai and Brian O'Neill",

year = "2006",

month = jun,

day = "1",

doi = "10.1080/17415990600646124",

language = "English",

volume = "27",

pages = "271--282",

journal = "Journal of Sulfur Chemistry",

issn = "1741-5993",

publisher = "Taylor & Francis",

number = "3",

}

TY - JOUR

T1 - Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides

AU - Wang, Haipeng

AU - Pring, Allan

AU - Wu, Fei

AU - Chen, Guorong

AU - Jiang, Jianhua

AU - Xia, Fang

AU - Zhang, Jian

AU - Ngothai, Yung

AU - O'Neill, Brian

PY - 2006/6/1

Y1 - 2006/6/1

N2 - Iron monosulfides, Fe1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.

AB - Iron monosulfides, Fe1-xS (0 < x < 0.125), are extremely complex in their chemical and physical behaviours, which are largely attributed to their nonstoichiometric nature and myriad superstructures. The chemical composition of Fe1-xS affects the polymorph formation for iron monosulfides, their mineral reactivity, surface sulfur fugacity, and thermal expansion. In this paper, the effects of cation vacancy and crystal superstructure on the thermodynamics of iron monosulfides are reviewed and discussed.

KW - Iron monosulfide

KW - Nonstoichiometry

KW - Pyrrhotite

KW - Vacancy

UR - http://www.scopus.com/inward/record.url?scp=33645559311&partnerID=8YFLogxK

U2 - 10.1080/17415990600646124

DO - 10.1080/17415990600646124

M3 - Short survey

AN - SCOPUS:33645559311

SN - 1741-5993

VL - 27

SP - 271

EP - 282

JO - Journal of Sulfur Chemistry

JF - Journal of Sulfur Chemistry

IS - 3

ER -

Effect of cation vacancy and crystal superstructure on thermodynamics of iron monosulfides

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this