Efficient solvent-free in situ tin-mediated homoallylation reactions

Philip C. Andrews, Anna C. Peatt, Colin L. Raston

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Various carbonyl compounds were converted to their corresponding homoallylic alcohols under ultrasonic irradiation and solvent free conditions, in the presence of metallic Sn and excess allyl bromide. Diallyltin(IV) dibromide was identified as the reactive species, with several allyl tin(II/IV) species being detected in the organic extracts of the reactions.

Original languageEnglish
Pages (from-to)7541-7543
Number of pages3
JournalTetrahedron Letters
Volume43
Issue number42
DOIs
Publication statusPublished - 14 Oct 2002
Externally publishedYes

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