Efficient solvent-free in situ tin-mediated homoallylation reactions

Philip C. Andrews; Anna C. Peatt; Colin L. Raston

doi:10.1016/S0040-4039(02)01811-7

Efficient solvent-free in situ tin-mediated homoallylation reactions

Philip C. Andrews
, Anna C. Peatt
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Various carbonyl compounds were converted to their corresponding homoallylic alcohols under ultrasonic irradiation and solvent free conditions, in the presence of metallic Sn and excess allyl bromide. Diallyltin(IV) dibromide was identified as the reactive species, with several allyl tin(II/IV) species being detected in the organic extracts of the reactions.

Original language	English
Pages (from-to)	7541-7543
Number of pages	3
Journal	Tetrahedron Letters
Volume	43
Issue number	42
DOIs	https://doi.org/10.1016/S0040-4039(02)01811-7
Publication status	Published - 14 Oct 2002
Externally published	Yes

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title = "Efficient solvent-free in situ tin-mediated homoallylation reactions",

abstract = "Various carbonyl compounds were converted to their corresponding homoallylic alcohols under ultrasonic irradiation and solvent free conditions, in the presence of metallic Sn and excess allyl bromide. Diallyltin(IV) dibromide was identified as the reactive species, with several allyl tin(II/IV) species being detected in the organic extracts of the reactions.",

author = "Andrews, \{Philip C.\} and Peatt, \{Anna C.\} and Raston, \{Colin L.\}",

year = "2002",

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doi = "10.1016/S0040-4039(02)01811-7",

language = "English",

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T1 - Efficient solvent-free in situ tin-mediated homoallylation reactions

AU - Andrews, Philip C.

AU - Peatt, Anna C.

AU - Raston, Colin L.

PY - 2002/10/14

Y1 - 2002/10/14

N2 - Various carbonyl compounds were converted to their corresponding homoallylic alcohols under ultrasonic irradiation and solvent free conditions, in the presence of metallic Sn and excess allyl bromide. Diallyltin(IV) dibromide was identified as the reactive species, with several allyl tin(II/IV) species being detected in the organic extracts of the reactions.

AB - Various carbonyl compounds were converted to their corresponding homoallylic alcohols under ultrasonic irradiation and solvent free conditions, in the presence of metallic Sn and excess allyl bromide. Diallyltin(IV) dibromide was identified as the reactive species, with several allyl tin(II/IV) species being detected in the organic extracts of the reactions.

UR - https://www.scopus.com/pages/publications/0037078430

U2 - 10.1016/S0040-4039(02)01811-7

DO - 10.1016/S0040-4039(02)01811-7

M3 - Article

AN - SCOPUS:0037078430

SN - 0040-4039

VL - 43

SP - 7541

EP - 7543

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 42

ER -

Efficient solvent-free in situ tin-mediated homoallylation reactions

Abstract

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