Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Mohamed Makha; Colin L. Raston; Alexandre N. Sobolev; Leonard J. Barbour; Peter Turner

doi:10.1039/b600550k

Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Mohamed Makha, Colin L. Raston, Alexandre N. Sobolev, Leonard J. Barbour, Peter Turner

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

p-Benzylcalix[4]arene forms inclusion complexes with o-carborane and C₆₀ wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 Å; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.

Original language	English
Pages (from-to)	306-308
Number of pages	3
Journal	CrystEngComm
Volume	8
Issue number	4
DOIs	https://doi.org/10.1039/b600550k
Publication status	Published - 12 May 2006
Externally published	Yes

Access to Document

10.1039/b600550kLicence: In Copyright

Cite this

@article{ecdb5e76667146889da89fdc204d428b,

title = "Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules",

abstract = "p-Benzylcalix[4]arene forms inclusion complexes with o-carborane and C60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 {\AA}; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.",

author = "Mohamed Makha and Raston, {Colin L.} and Sobolev, {Alexandre N.} and Barbour, {Leonard J.} and Peter Turner",

year = "2006",

month = may,

day = "12",

doi = "10.1039/b600550k",

language = "English",

volume = "8",

pages = "306--308",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

AU - Makha, Mohamed

AU - Raston, Colin L.

AU - Sobolev, Alexandre N.

AU - Barbour, Leonard J.

AU - Turner, Peter

PY - 2006/5/12

Y1 - 2006/5/12

N2 - p-Benzylcalix[4]arene forms inclusion complexes with o-carborane and C60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 Å; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.

AB - p-Benzylcalix[4]arene forms inclusion complexes with o-carborane and C60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 Å; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.

UR - http://www.scopus.com/inward/record.url?scp=33646343016&partnerID=8YFLogxK

U2 - 10.1039/b600550k

DO - 10.1039/b600550k

M3 - Article

AN - SCOPUS:33646343016

SN - 1466-8033

VL - 8

SP - 306

EP - 308

JO - CrystEngComm

JF - CrystEngComm

IS - 4

ER -

Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Abstract

Access to Document

Other files and links

Fingerprint

Cite this