TY - JOUR
T1 - Experimental evaluation of the luminescence performance of fired clay brick coated with SrAl2O4: Eu/Dy phosphor
AU - Gencel, Osman
AU - Danish, Aamar
AU - Yilmaz, Mukremin
AU - Erdogmus, Ertugrul
AU - Sutcu, Mucahit
AU - Ozbakkaloglu, Togay
AU - Gholampour, Aliakbar
PY - 2022/11/15
Y1 - 2022/11/15
N2 - This study evaluates the luminescence performance of fired clay bricks coated with SrAl2O4:Eu/Dy phosphor. To do so, SrAl2O4:Eu/Dy phosphor was first produced using the traditional solid-state reaction synthesis technique. The prepared phosphor was then used for coating fired clay bricks to analyze the luminescence performance via spectral analysis, decay characteristics, and microstructure of the bricks. The results reveal that excitation and emission spectra of the phosphor coated bricks range from 200 to 480 nm and 455 to 650 nm, respectively, suggesting that the phosphor coated bricks have the capacity of absorbing light with a wide range of wavelengths. The peak wavelength projected at 511 nm in the emission spectrum is achieved, which indicates 4f65 d1-4f7 transition of Europium (Eu2+). The repeated excitation and deexcitation of Eu2+ by using hole traps and trap levels offered by Dysprosium (Dy3+), exist between the ground and the excited state of Eu2+ leads to luminescent phenomenon. Moreover, the decay characteristics has revealed that phosphor coated bricks can emit light for a considerable amount of time (>8.5 min) upon the removal of the excitation source. The results reveal that phosphor coated bricks has the potential of increasing energy efficiency of residential and commercial buildings.
AB - This study evaluates the luminescence performance of fired clay bricks coated with SrAl2O4:Eu/Dy phosphor. To do so, SrAl2O4:Eu/Dy phosphor was first produced using the traditional solid-state reaction synthesis technique. The prepared phosphor was then used for coating fired clay bricks to analyze the luminescence performance via spectral analysis, decay characteristics, and microstructure of the bricks. The results reveal that excitation and emission spectra of the phosphor coated bricks range from 200 to 480 nm and 455 to 650 nm, respectively, suggesting that the phosphor coated bricks have the capacity of absorbing light with a wide range of wavelengths. The peak wavelength projected at 511 nm in the emission spectrum is achieved, which indicates 4f65 d1-4f7 transition of Europium (Eu2+). The repeated excitation and deexcitation of Eu2+ by using hole traps and trap levels offered by Dysprosium (Dy3+), exist between the ground and the excited state of Eu2+ leads to luminescent phenomenon. Moreover, the decay characteristics has revealed that phosphor coated bricks can emit light for a considerable amount of time (>8.5 min) upon the removal of the excitation source. The results reveal that phosphor coated bricks has the potential of increasing energy efficiency of residential and commercial buildings.
KW - Luminescence performance
KW - SrAl2O4:Eu/Dy phosphor
KW - Fired clay brick
KW - Decay characteristics
KW - Excitation and emission spectrum
UR - http://www.scopus.com/inward/record.url?scp=85136147520&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2022.07.255
DO - 10.1016/j.ceramint.2022.07.255
M3 - Article
SN - 0272-8842
VL - 48
SP - 33167
EP - 33176
JO - Ceramics International
JF - Ceramics International
IS - 22
ER -