Experimental evaluation of the luminescence performance of fired clay brick coated with SrAl2O4: Eu/Dy phosphor

Osman Gencel, Aamar Danish, Mukremin Yilmaz, Ertugrul Erdogmus, Mucahit Sutcu, Togay Ozbakkaloglu, Aliakbar Gholampour

Research output: Contribution to journalArticlepeer-review

Abstract

This study evaluates the luminescence performance of fired clay bricks coated with SrAl2O4:Eu/Dy phosphor. To do so, SrAl2O4:Eu/Dy phosphor was first produced using the traditional solid-state reaction synthesis technique. The prepared phosphor was then used for coating fired clay bricks to analyze the luminescence performance via spectral analysis, decay characteristics, and microstructure of the bricks. The results reveal that excitation and emission spectra of the phosphor coated bricks range from 200 to 480 nm and 455 to 650 nm, respectively, suggesting that the phosphor coated bricks have the capacity of absorbing light with a wide range of wavelengths. The peak wavelength projected at 511 nm in the emission spectrum is achieved, which indicates 4f65 d1-4f7 transition of Europium (Eu2+). The repeated excitation and deexcitation of Eu2+ by using hole traps and trap levels offered by Dysprosium (Dy3+), exist between the ground and the excited state of Eu2+ leads to luminescent phenomenon. Moreover, the decay characteristics has revealed that phosphor coated bricks can emit light for a considerable amount of time (>8.5 min) upon the removal of the excitation source. The results reveal that phosphor coated bricks has the potential of increasing energy efficiency of residential and commercial buildings.
Original languageEnglish
Pages (from-to)33167-33176
Number of pages10
JournalCeramics International
Volume48
Issue number22
Early online date3 Aug 2022
DOIs
Publication statusPublished - 15 Nov 2022

Keywords

  • Luminescence performance
  • SrAl2O4:Eu/Dy phosphor
  • Fired clay brick
  • Decay characteristics
  • Excitation and emission spectrum

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