Facile insertion of CO2 into metal-phenoxide bonds

Sait Elmas; Afzal Subhani; Henning Vogt; Walter Leitner; Thomas Müller

doi:10.1039/c3gc40147b

Facile insertion of CO2 into metal-phenoxide bonds

Sait Elmas, Afzal Subhani, Henning Vogt, Walter Leitner, Thomas Müller

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The activation of CO₂ is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO₂. Following the activation of CO₂ with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO₂ into metal-phenoxide bonds was revealed.

Original language	English
Pages (from-to)	1356-1360
Number of pages	5
Journal	Green Chemistry
Volume	15
Issue number	5
DOIs	https://doi.org/10.1039/c3gc40147b
Publication status	Published - May 2013
Externally published	Yes

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title = "Facile insertion of CO2 into metal-phenoxide bonds",

abstract = "The activation of CO2 is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO2. Following the activation of CO2 with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO2 into metal-phenoxide bonds was revealed.",

author = "Sait Elmas and Afzal Subhani and Henning Vogt and Walter Leitner and Thomas M{\"u}ller",

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doi = "10.1039/c3gc40147b",

language = "English",

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AU - Elmas, Sait

AU - Subhani, Afzal

AU - Vogt, Henning

AU - Leitner, Walter

AU - Müller, Thomas

PY - 2013/5

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N2 - The activation of CO2 is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO2. Following the activation of CO2 with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO2 into metal-phenoxide bonds was revealed.

AB - The activation of CO2 is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO2. Following the activation of CO2 with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO2 into metal-phenoxide bonds was revealed.

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U2 - 10.1039/c3gc40147b

DO - 10.1039/c3gc40147b

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VL - 15

SP - 1356

EP - 1360

JO - Green Chemistry

JF - Green Chemistry

IS - 5

ER -

Facile insertion of CO2 into metal-phenoxide bonds

Abstract

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