Helical polymeric network of [ZnCl 
                        2
                        (4′-aryl-4, 2′-6′,4-terpyridine)] 
                        n

Gareth W.V. Cave; Colin L. Raston

doi:10.1016/S1472-7862(03)00087-X

Helical polymeric network of [ZnCl ₂ (4′-aryl-4, 2′-6′,4-terpyridine)] _n

Gareth W.V. Cave
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The coordination polymer formed by the addition of zinc(II)chloride to 4′-(4‴-octyloxyphenyl)-4,2′-6′,4″- terpyridine (readily prepared using green chemistry principles) has been structurally authenticated using single crystal X-ray diffraction and microanalysis techniques. The polymeric network adopts a layered helical zigzag arrangement about a distorted tetrahedral Zn(II) centre, forming channels of inter-digitated alkyl chains.

Original language	English
Pages (from-to)	317-319
Number of pages	3
Journal	Journal of Supramolecular Chemistry
Volume	2
Issue number	1-3
DOIs	https://doi.org/10.1016/S1472-7862(03)00087-X
Publication status	Published - 1 Jan 2002
Externally published	Yes

Keywords

Coordination chemistry
Supramolecular chemistry
Terpyridine
Zinc

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abstract = "The coordination polymer formed by the addition of zinc(II)chloride to 4′-(4‴-octyloxyphenyl)-4,2′-6′,4″- terpyridine (readily prepared using green chemistry principles) has been structurally authenticated using single crystal X-ray diffraction and microanalysis techniques. The polymeric network adopts a layered helical zigzag arrangement about a distorted tetrahedral Zn(II) centre, forming channels of inter-digitated alkyl chains.",

keywords = "Coordination chemistry, Supramolecular chemistry, Terpyridine, Zinc",

author = "Cave, \{Gareth W.V.\} and Raston, \{Colin L.\}",

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doi = "10.1016/S1472-7862(03)00087-X",

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AU - Raston, Colin L.

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Y1 - 2002/1/1

N2 - The coordination polymer formed by the addition of zinc(II)chloride to 4′-(4‴-octyloxyphenyl)-4,2′-6′,4″- terpyridine (readily prepared using green chemistry principles) has been structurally authenticated using single crystal X-ray diffraction and microanalysis techniques. The polymeric network adopts a layered helical zigzag arrangement about a distorted tetrahedral Zn(II) centre, forming channels of inter-digitated alkyl chains.

AB - The coordination polymer formed by the addition of zinc(II)chloride to 4′-(4‴-octyloxyphenyl)-4,2′-6′,4″- terpyridine (readily prepared using green chemistry principles) has been structurally authenticated using single crystal X-ray diffraction and microanalysis techniques. The polymeric network adopts a layered helical zigzag arrangement about a distorted tetrahedral Zn(II) centre, forming channels of inter-digitated alkyl chains.

KW - Coordination chemistry

KW - Supramolecular chemistry

KW - Terpyridine

KW - Zinc

UR - https://www.scopus.com/pages/publications/0041697017

U2 - 10.1016/S1472-7862(03)00087-X

DO - 10.1016/S1472-7862(03)00087-X

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AN - SCOPUS:0041697017

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JO - Journal of Supramolecular Chemistry

JF - Journal of Supramolecular Chemistry

IS - 1-3

ER -

Helical polymeric network of [ZnCl ₂ (4′-aryl-4, 2′-6′,4-terpyridine)] _n

Abstract

Keywords

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