High-resolution fourier transform infrared spectroscopy of nitrosyl fluoride

C. J. Evans; D. McNaughton; P. Dexter; W. Lawrance

doi:10.1006/jmsp.1997.7470

High-resolution fourier transform infrared spectroscopy of nitrosyl fluoride

C. J. Evans, D. McNaughton, P. Dexter, W. Lawrance

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The high-resolution FTIR spectrum of FNO has been recorded and the rovibrational structure of the essentially unperturbed ν₃, 2ν₃, and ν₁ + ν₃ cold bands and the 2ν₃ ← ν₃, ν₂ + ν₃ ← ν₃, and ν₁ + ν₂ + ν₃ ← ν₃ hot bands has been analyzed. The perturbed bands ν₁ and ν₁ + ν₂ have been assigned and the data analyzed by fitting the transitions with the dark states ν₂ + 2ν₃ and 2ν₂ + 2ν₃. Parameters for both light and dark states together with Coriolis coupling parameters have been determined.

Original language	English
Pages (from-to)	75-81
Number of pages	7
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	187
Issue number	1
DOIs	https://doi.org/10.1006/jmsp.1997.7470
Publication status	Published - Jan 1998

Access to Document

10.1006/jmsp.1997.7470Licence: In Copyright

Cite this

@article{8afbbfd25e184b92a2c1fa628b8dc094,

title = "High-resolution fourier transform infrared spectroscopy of nitrosyl fluoride",

abstract = "The high-resolution FTIR spectrum of FNO has been recorded and the rovibrational structure of the essentially unperturbed ν3, 2ν3, and ν1 + ν3 cold bands and the 2ν3 ← ν3, ν2 + ν3 ← ν3, and ν1 + ν2 + ν3 ← ν3 hot bands has been analyzed. The perturbed bands ν1 and ν1 + ν2 have been assigned and the data analyzed by fitting the transitions with the dark states ν2 + 2ν3 and 2ν2 + 2ν3. Parameters for both light and dark states together with Coriolis coupling parameters have been determined.",

author = "Evans, {C. J.} and D. McNaughton and P. Dexter and W. Lawrance",

year = "1998",

month = jan,

doi = "10.1006/jmsp.1997.7470",

language = "English",

volume = "187",

pages = "75--81",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

number = "1",

}

TY - JOUR

T1 - High-resolution fourier transform infrared spectroscopy of nitrosyl fluoride

AU - Evans, C. J.

AU - McNaughton, D.

AU - Dexter, P.

AU - Lawrance, W.

PY - 1998/1

Y1 - 1998/1

N2 - The high-resolution FTIR spectrum of FNO has been recorded and the rovibrational structure of the essentially unperturbed ν3, 2ν3, and ν1 + ν3 cold bands and the 2ν3 ← ν3, ν2 + ν3 ← ν3, and ν1 + ν2 + ν3 ← ν3 hot bands has been analyzed. The perturbed bands ν1 and ν1 + ν2 have been assigned and the data analyzed by fitting the transitions with the dark states ν2 + 2ν3 and 2ν2 + 2ν3. Parameters for both light and dark states together with Coriolis coupling parameters have been determined.

AB - The high-resolution FTIR spectrum of FNO has been recorded and the rovibrational structure of the essentially unperturbed ν3, 2ν3, and ν1 + ν3 cold bands and the 2ν3 ← ν3, ν2 + ν3 ← ν3, and ν1 + ν2 + ν3 ← ν3 hot bands has been analyzed. The perturbed bands ν1 and ν1 + ν2 have been assigned and the data analyzed by fitting the transitions with the dark states ν2 + 2ν3 and 2ν2 + 2ν3. Parameters for both light and dark states together with Coriolis coupling parameters have been determined.

UR - http://www.scopus.com/inward/record.url?scp=0346016753&partnerID=8YFLogxK

U2 - 10.1006/jmsp.1997.7470

DO - 10.1006/jmsp.1997.7470

M3 - Article

AN - SCOPUS:0346016753

SN - 0022-2852

VL - 187

SP - 75

EP - 81

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 1

ER -

High-resolution fourier transform infrared spectroscopy of nitrosyl fluoride

Abstract

Access to Document

Other files and links

Fingerprint

Cite this