TY - JOUR
T1 - Highly selective Pd-Cu/ZnAl2O4 catalyst for hydrogen production
AU - Mierczynski, Pawel
AU - Vasilev, Krasimir
AU - Mierczynska, Agnieszka
AU - Maniukiewicz, Waldemar
AU - Maniecki, Tomasz P.
PY - 2014/6/5
Y1 - 2014/6/5
N2 - This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl2O4 during reduction in 5%H2-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.
AB - This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl2O4 during reduction in 5%H2-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.
KW - Alloy
KW - Bimetallic catalyst
KW - Monometallic catalyst
KW - Pd-Cu
UR - http://www.scopus.com/inward/record.url?scp=84900456091&partnerID=8YFLogxK
U2 - 10.1016/j.apcata.2014.04.011
DO - 10.1016/j.apcata.2014.04.011
M3 - Article
AN - SCOPUS:84900456091
SN - 0926-860X
VL - 479
SP - 26
EP - 34
JO - Applied Catalysis A: General
JF - Applied Catalysis A: General
ER -