Highly selective Pd-Cu/ZnAl2O4 catalyst for hydrogen production

Pawel Mierczynski; Krasimir Vasilev; Agnieszka Mierczynska; Waldemar Maniukiewicz; Tomasz P. Maniecki

doi:10.1016/j.apcata.2014.04.011

Highly selective Pd-Cu/ZnAl₂O₄ catalyst for hydrogen production

Pawel Mierczynski, Krasimir Vasilev, Agnieszka Mierczynska, Waldemar Maniukiewicz, Tomasz P. Maniecki

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl₂O₄ during reduction in 5%H₂-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.

Original language	English
Pages (from-to)	26-34
Number of pages	9
Journal	Applied Catalysis A: General
Volume	479
DOIs	https://doi.org/10.1016/j.apcata.2014.04.011
Publication status	Published - 5 Jun 2014
Externally published	Yes

Keywords

Alloy
Bimetallic catalyst
Monometallic catalyst
Pd-Cu

Access to Document

10.1016/j.apcata.2014.04.011Licence: In Copyright

Cite this

@article{fc704db09f5247f88b0c897400a1d833,

title = "Highly selective Pd-Cu/ZnAl2O4 catalyst for hydrogen production",

abstract = "This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl2O4 during reduction in 5%H2-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.",

keywords = "Alloy, Bimetallic catalyst, Monometallic catalyst, Pd-Cu",

author = "Pawel Mierczynski and Krasimir Vasilev and Agnieszka Mierczynska and Waldemar Maniukiewicz and Maniecki, {Tomasz P.}",

year = "2014",

month = jun,

day = "5",

doi = "10.1016/j.apcata.2014.04.011",

language = "English",

volume = "479",

pages = "26--34",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Highly selective Pd-Cu/ZnAl2O4 catalyst for hydrogen production

AU - Mierczynski, Pawel

AU - Vasilev, Krasimir

AU - Mierczynska, Agnieszka

AU - Maniukiewicz, Waldemar

AU - Maniecki, Tomasz P.

PY - 2014/6/5

Y1 - 2014/6/5

N2 - This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl2O4 during reduction in 5%H2-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.

AB - This paper deals with the study of the bimetallic Pd-Cu and monometallic Cu catalyst in steam reforming of methanol. FTIR spectroscopy, X-ray diffraction (XRD) and XPS techniques were used to characterize both mono and bimetallic catalysts. This study presents evidence of Pd-Cu formation in copper catalysts supported on spinel structure ZnAl2O4 during reduction in 5%H2-95%Ar mixture at 300 °C in the presence of palladium. The intermetallic compound is formed by a spillover effect between Pd and Cu.

KW - Alloy

KW - Bimetallic catalyst

KW - Monometallic catalyst

KW - Pd-Cu

UR - http://www.scopus.com/inward/record.url?scp=84900456091&partnerID=8YFLogxK

U2 - 10.1016/j.apcata.2014.04.011

DO - 10.1016/j.apcata.2014.04.011

M3 - Article

AN - SCOPUS:84900456091

SN - 0926-860X

VL - 479

SP - 26

EP - 34

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

ER -

Highly selective Pd-Cu/ZnAl₂O₄ catalyst for hydrogen production

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this