Hirshfeld surface analysis of phosphonium salts

Irene Ling, Yatimah Alias, Alexandre Sobolev, Colin Raston

    Research output: Contribution to journalArticle

    15 Citations (Scopus)

    Abstract

    Structurally authenticated phosphonium salts yielded from the treatment of (phosphoniumn+)(Cl- or Br-)n and (imidazoliumn+)(X-)n, n = 1 or 2 have been examined using Hirshfeld surface analysis, revealing the domination of C-H⋯X non-classical hydrogen-bonding between the cations and anions. The crystalline salts of (phosphoniumn+)(X-)n (X- = [SCN]-, [N(CN)2]-, [C(CN) 3]-, [PF6]-, [CF3SO 3]- or [N(CF3SO2)2] -) were formed by metathetical exchange in the presence of p-sulfonatocalix[4]arene and aquated gadolinium ions.

    Original languageEnglish
    Pages (from-to)4321-4327
    Number of pages7
    JournalCrystEngComm
    Volume12
    Issue number12
    DOIs
    Publication statusPublished - 2010

    Fingerprint Dive into the research topics of 'Hirshfeld surface analysis of phosphonium salts'. Together they form a unique fingerprint.

  • Cite this