Hypervalent silicon via thermolysis of a cadmium amide: Thermally stable magnesium and zinc amides [ML2], L = N(8-quinolyl)(SiMe3)

Lutz M. Englehardt; Peter C. Junk; Wyona C. Patalinghug; Rodney E. Sue; Colin L. Raston; Brian W. Skelton; Allan H. White

doi:10.1039/C39910000930

Hypervalent silicon via thermolysis of a cadmium amide: Thermally stable magnesium and zinc amides [ML₂], L = N(8-quinolyl)(SiMe₃)

Lutz M. Englehardt, Peter C. Junk, Wyona C. Patalinghug, Rodney E. Sue, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Structurally authenticated N-functionalized amides [ML₂], L = N(8-quinolyl)(SiMe₃), derived from the reaction of 8-(trimethylsilylamino)quinoline with MgBuⁿBu^s or ZnEt₂ in hexane are sublimable in vacuo at 175°C; the corresponding cadmium analogue, derived from CdCl₂ and LiL, decomposes at ca. 240°C in vacuo yielding CdMe₂ and a novel dimeric five coordinate silicon species [Me₂Si(μ-N-C ₉H₆N)(μ-N-C₉H₆N)SiMe ₂] possessing an Si₂N₂ ring system, Si-N _bridging (mean) 1.77 Å, Si-N_neutral 2.33(1) Å.

Original language	English
Pages (from-to)	930-932
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39910000930
Publication status	Published - 15 Jul 1991
Externally published	Yes

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title = "Hypervalent silicon via thermolysis of a cadmium amide: Thermally stable magnesium and zinc amides [ML2], L = N(8-quinolyl)(SiMe3)",

abstract = "Structurally authenticated N-functionalized amides [ML2], L = N(8-quinolyl)(SiMe3), derived from the reaction of 8-(trimethylsilylamino)quinoline with MgBunBus or ZnEt2 in hexane are sublimable in vacuo at 175°C; the corresponding cadmium analogue, derived from CdCl2 and LiL, decomposes at ca. 240°C in vacuo yielding CdMe2 and a novel dimeric five coordinate silicon species [Me2Si(μ-N-C 9H6N)(μ-N-C9H6N)SiMe 2] possessing an Si2N2 ring system, Si-N bridging (mean) 1.77 {\AA}, Si-Nneutral 2.33(1) {\AA}.",

author = "Englehardt, {Lutz M.} and Junk, {Peter C.} and Patalinghug, {Wyona C.} and Sue, {Rodney E.} and Raston, {Colin L.} and Skelton, {Brian W.} and White, {Allan H.}",

year = "1991",

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doi = "10.1039/C39910000930",

language = "English",

pages = "930--932",

journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Hypervalent silicon via thermolysis of a cadmium amide

T2 - Thermally stable magnesium and zinc amides [ML2], L = N(8-quinolyl)(SiMe3)

AU - Englehardt, Lutz M.

AU - Junk, Peter C.

AU - Patalinghug, Wyona C.

AU - Sue, Rodney E.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1991/7/15

Y1 - 1991/7/15

N2 - Structurally authenticated N-functionalized amides [ML2], L = N(8-quinolyl)(SiMe3), derived from the reaction of 8-(trimethylsilylamino)quinoline with MgBunBus or ZnEt2 in hexane are sublimable in vacuo at 175°C; the corresponding cadmium analogue, derived from CdCl2 and LiL, decomposes at ca. 240°C in vacuo yielding CdMe2 and a novel dimeric five coordinate silicon species [Me2Si(μ-N-C 9H6N)(μ-N-C9H6N)SiMe 2] possessing an Si2N2 ring system, Si-N bridging (mean) 1.77 Å, Si-Nneutral 2.33(1) Å.

AB - Structurally authenticated N-functionalized amides [ML2], L = N(8-quinolyl)(SiMe3), derived from the reaction of 8-(trimethylsilylamino)quinoline with MgBunBus or ZnEt2 in hexane are sublimable in vacuo at 175°C; the corresponding cadmium analogue, derived from CdCl2 and LiL, decomposes at ca. 240°C in vacuo yielding CdMe2 and a novel dimeric five coordinate silicon species [Me2Si(μ-N-C 9H6N)(μ-N-C9H6N)SiMe 2] possessing an Si2N2 ring system, Si-N bridging (mean) 1.77 Å, Si-Nneutral 2.33(1) Å.

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JO - Journal of the Chemical Society, Chemical Communications

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Hypervalent silicon via thermolysis of a cadmium amide: Thermally stable magnesium and zinc amides [ML₂], L = N(8-quinolyl)(SiMe₃)

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