Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface

Anand Kumar; Thomas Ceme; Gunther G. Andersson

doi:10.1016/B978-0-323-85669-0.00055-6

Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface

Anand Kumar, Thomas Ceme, Gunther G. Andersson

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

1 Citation (Scopus)

Abstract

A summary of derivations related to the interfacial thermodynamics is provided, highlighting the contact angle as a measure to determine interfacial tension directly at the solid-liquid interfaces. Techniques used to directly measure the interfacial excess (or interfacial concentration) at the solid-liquid interfaces are described with examples detailing such measurements. Developing techniques, that can measure the direct interfacial concentration at the solid-liquid interfaces with elemental and chemical specificity are also highlighted here.

Original language	English
Title of host publication	Encyclopedia of Solid-Liquid Interfaces
Subtitle of host publication	Volume 2 - Phenomena and Understanding
Editors	Klaus Wandelt, Gianlorenzo Bussetti, Gunther Andersson, David Starr, Hendrik Bluhm
Place of Publication	Amsterdam
Publisher	Elsevier
Pages	255-267
Number of pages	13
Volume	2
ISBN (Electronic)	978-0-323-85670-6
ISBN (Print)	978-0-323-85669-0
DOIs	https://doi.org/10.1016/B978-0-323-85669-0.00055-6
Publication status	Published - 2024

Keywords

Contact angle
Gibbs adsorption isotherm
Interfacial entropy
Interfacial excess
Interfacial tension
Interfacial thermodynamics
Neutral impact collision ion scattering spectroscopy
Neutron reflectivity
Non-linear optical techniques
Solid-liquid interface
Wilhelmy plate method
X-ray photoelectron spectroscopy
X-ray reflectivity

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Kumar, A., Ceme, T., & Andersson, G. G. (2024). Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface. In K. Wandelt, G. Bussetti, G. Andersson, D. Starr, & H. Bluhm (Eds.), Encyclopedia of Solid-Liquid Interfaces: Volume 2 - Phenomena and Understanding (Vol. 2, pp. 255-267). Elsevier. https://doi.org/10.1016/B978-0-323-85669-0.00055-6

Kumar, Anand ; Ceme, Thomas ; Andersson, Gunther G. / Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface. Encyclopedia of Solid-Liquid Interfaces: Volume 2 - Phenomena and Understanding. editor / Klaus Wandelt ; Gianlorenzo Bussetti ; Gunther Andersson ; David Starr ; Hendrik Bluhm. Vol. 2 Amsterdam : Elsevier, 2024. pp. 255-267

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abstract = "A summary of derivations related to the interfacial thermodynamics is provided, highlighting the contact angle as a measure to determine interfacial tension directly at the solid-liquid interfaces. Techniques used to directly measure the interfacial excess (or interfacial concentration) at the solid-liquid interfaces are described with examples detailing such measurements. Developing techniques, that can measure the direct interfacial concentration at the solid-liquid interfaces with elemental and chemical specificity are also highlighted here.",

keywords = "Contact angle, Gibbs adsorption isotherm, Interfacial entropy, Interfacial excess, Interfacial tension, Interfacial thermodynamics, Neutral impact collision ion scattering spectroscopy, Neutron reflectivity, Non-linear optical techniques, Solid-liquid interface, Wilhelmy plate method, X-ray photoelectron spectroscopy, X-ray reflectivity",

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Kumar, A , Ceme, T & Andersson, GG 2024, Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface. in K Wandelt, G Bussetti, G Andersson, D Starr & H Bluhm (eds), Encyclopedia of Solid-Liquid Interfaces: Volume 2 - Phenomena and Understanding. vol. 2, Elsevier, Amsterdam, pp. 255-267. https://doi.org/10.1016/B978-0-323-85669-0.00055-6

Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface. / Kumar, Anand ; Ceme, Thomas ; Andersson, Gunther G.
Encyclopedia of Solid-Liquid Interfaces: Volume 2 - Phenomena and Understanding. ed. / Klaus Wandelt; Gianlorenzo Bussetti; Gunther Andersson; David Starr; Hendrik Bluhm. Vol. 2 Amsterdam: Elsevier, 2024. p. 255-267.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface

AU - Kumar, Anand

AU - Ceme, Thomas

AU - Andersson, Gunther G.

PY - 2024

Y1 - 2024

N2 - A summary of derivations related to the interfacial thermodynamics is provided, highlighting the contact angle as a measure to determine interfacial tension directly at the solid-liquid interfaces. Techniques used to directly measure the interfacial excess (or interfacial concentration) at the solid-liquid interfaces are described with examples detailing such measurements. Developing techniques, that can measure the direct interfacial concentration at the solid-liquid interfaces with elemental and chemical specificity are also highlighted here.

AB - A summary of derivations related to the interfacial thermodynamics is provided, highlighting the contact angle as a measure to determine interfacial tension directly at the solid-liquid interfaces. Techniques used to directly measure the interfacial excess (or interfacial concentration) at the solid-liquid interfaces are described with examples detailing such measurements. Developing techniques, that can measure the direct interfacial concentration at the solid-liquid interfaces with elemental and chemical specificity are also highlighted here.

KW - Contact angle

KW - Gibbs adsorption isotherm

KW - Interfacial entropy

KW - Interfacial excess

KW - Interfacial tension

KW - Interfacial thermodynamics

KW - Neutral impact collision ion scattering spectroscopy

KW - Neutron reflectivity

KW - Non-linear optical techniques

KW - Solid-liquid interface

KW - Wilhelmy plate method

KW - X-ray photoelectron spectroscopy

KW - X-ray reflectivity

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UR - http://purl.org/au-research/grants/ARC/DP190100788

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DO - 10.1016/B978-0-323-85669-0.00055-6

M3 - Chapter

AN - SCOPUS:85191849643

SN - 978-0-323-85669-0

VL - 2

SP - 255

EP - 267

BT - Encyclopedia of Solid-Liquid Interfaces

A2 - Wandelt, Klaus

A2 - Bussetti, Gianlorenzo

A2 - Andersson, Gunther

A2 - Starr, David

A2 - Bluhm, Hendrik

PB - Elsevier

CY - Amsterdam

ER -

Kumar A , Ceme T , Andersson GG. Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface. In Wandelt K, Bussetti G, Andersson G, Starr D, Bluhm H, editors, Encyclopedia of Solid-Liquid Interfaces: Volume 2 - Phenomena and Understanding. Vol. 2. Amsterdam: Elsevier. 2024. p. 255-267 Epub 2023 Aug 30. doi: 10.1016/B978-0-323-85669-0.00055-6

Interfacial excess, interfacial tension, interfacial entropy, and tools to measure thermodynamic quantity at the solid-liquid interface

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