Intramolecular [2 + 2] photoaddition of a 1,7-diene

Kevin D. Croft, Emilio L. Ghisalberti, Phillip R. Jefferies, Alan D. Stuart, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Intramolecular photoaddition of the 1,7-diene system in 4-(1,5-dimethylhex-4-enyl)cyclohex-2-enone (3) yielded, inter alia, two ketones containing the tricyclo[5.3.1.05, 11]undecan-8-one system. The structure and stereochemistry of these ketones has been determined from X-ray crystallographic analyses of suitable derivatives.

Original languageEnglish
Pages (from-to)1473-1480
Number of pages8
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number11
Publication statusPublished - 1981
Externally publishedYes

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