'Inverse crown ether' complexes: Extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH3(SiMe2) interactions

Alan R. Kennedy, Robert E. Mulvey, Colin L. Raston, Brett A. Roberts, René B. Rowlings

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

Original languageEnglish
Pages (from-to)353-354
Number of pages2
JournalChemical Communications
Issue number4
DOIs
Publication statusPublished - 21 Feb 1999
Externally publishedYes

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