'Inverse crown ether' complexes: Extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH3(SiMe2) interactions

Alan R. Kennedy; Robert E. Mulvey; Colin L. Raston; Brett A. Roberts; René B. Rowlings

doi:10.1039/a809681c

'Inverse crown ether' complexes: Extension to potassium through the synthesis of [{[(Me₃Si)₂N]₄K₂Mg₂(O₂)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH₃(SiMe₂) interactions

Alan R. Kennedy, Robert E. Mulvey, Colin L. Raston, Brett A. Roberts, René B. Rowlings

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N₄K₂Mg₂)²⁺ octagonal ring framework surrounding a dianionic (O₂)^2- core.

Original language	English
Pages (from-to)	353-354
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/a809681c
Publication status	Published - 21 Feb 1999
Externally published	Yes

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Kennedy, A. R., Mulvey, R. E., Raston, C. L., Roberts, B. A., & Rowlings, R. B. (1999). 'Inverse crown ether' complexes: Extension to potassium through the synthesis of [{[(Me₃Si)₂N]₄K₂Mg₂(O₂)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH₃(SiMe₂) interactions. Chemical Communications, (4), 353-354. https://doi.org/10.1039/a809681c

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abstract = "The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.",

author = "Kennedy, {Alan R.} and Mulvey, {Robert E.} and Raston, {Colin L.} and Roberts, {Brett A.} and Rowlings, {Ren{\'e} B.}",

year = "1999",

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doi = "10.1039/a809681c",

language = "English",

pages = "353--354",

journal = "Chemical Communications",

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number = "4",

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'Inverse crown ether' complexes: Extension to potassium through the synthesis of [{[(Me₃Si)₂N]₄K₂Mg₂(O₂)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH₃(SiMe₂) interactions. / Kennedy, Alan R.; Mulvey, Robert E.; Raston, Colin L. et al.
In: Chemical Communications, No. 4, 21.02.1999, p. 353-354.

Research output: Contribution to journal › Article › peer-review

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T2 - Extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}(∞)], a peroxo-centred macrocycle linked into infinite chains by intermolecular K···CH3(SiMe2) interactions

AU - Kennedy, Alan R.

AU - Mulvey, Robert E.

AU - Raston, Colin L.

AU - Roberts, Brett A.

AU - Rowlings, René B.

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