Lanthanide-induced helical arrays of [{Co(III) sepulchrate} ∩ {p-sulfonatocalix[4]arene}] supermolecules

Christopher B. Smith; Leonard J. Barbour; Mohamed Makha; Colin L. Raston; Alexandre N. Sobolev

doi:10.1039/b515580k

Lanthanide-induced helical arrays of [{Co(III) sepulchrate} ∩ {p-sulfonatocalix[4]arene}] supermolecules

Christopher B. Smith, Leonard J. Barbour, Mohamed Makha, Colin L. Raston, Alexandre N. Sobolev

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

In the presence of lanthanide ions, a Co(III) sepulchrate cation [Co(diHOsar)]³⁺ and sodium p-sulfonatocalix[4]arene form a 1: 1 host-guest complex which is self-assembled into a zeolite-like lattice network comprised of parallel, single stranded helices.

Original language	English
Pages (from-to)	950-952
Number of pages	3
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b515580k
Publication status	Published - 28 Feb 2006
Externally published	Yes

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abstract = "In the presence of lanthanide ions, a Co(III) sepulchrate cation [Co(diHOsar)]3+ and sodium p-sulfonatocalix[4]arene form a 1: 1 host-guest complex which is self-assembled into a zeolite-like lattice network comprised of parallel, single stranded helices.",

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AU - Makha, Mohamed

AU - Raston, Colin L.

AU - Sobolev, Alexandre N.

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AB - In the presence of lanthanide ions, a Co(III) sepulchrate cation [Co(diHOsar)]3+ and sodium p-sulfonatocalix[4]arene form a 1: 1 host-guest complex which is self-assembled into a zeolite-like lattice network comprised of parallel, single stranded helices.

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Lanthanide-induced helical arrays of [{Co(III) sepulchrate} ∩ {p-sulfonatocalix[4]arene}] supermolecules

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