Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine

Colin L. Raston; Brian W. Skelton; Claire R. Whitaker; Allan H. White

doi:10.1071/CH9881925

Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine

Colin L. Raston, Brian W. Skelton, Claire R. Whitaker, Allan H. White

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Crystalline adducts of the lithium(I) halides, LiX (X = Cl, Br, I) with N, N, N′, N′-tetramethylethyl- enediamine (tmeda) have been synthesized and characterized by single-crystal X-ray studies. Both bromide and iodide form 1:1 adducts which are μ, μ′-dihalo-bridged binuclear species, [(tmeda)LiX₁ unit solvated by chelating and bridging tmeda units.

Original language	English
Pages (from-to)	1925-1934
Number of pages	10
Journal	Australian Journal of Chemistry
Volume	41
Issue number	12
DOIs	https://doi.org/10.1071/CH9881925
Publication status	Published - 1988
Externally published	Yes

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title = "Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine",

abstract = "Crystalline adducts of the lithium(I) halides, LiX (X = Cl, Br, I) with N, N, N′, N′-tetramethylethyl- enediamine (tmeda) have been synthesized and characterized by single-crystal X-ray studies. Both bromide and iodide form 1:1 adducts which are μ, μ′-dihalo-bridged binuclear species, [(tmeda)LiX1 unit solvated by chelating and bridging tmeda units.",

author = "Raston, {Colin L.} and Skelton, {Brian W.} and Whitaker, {Claire R.} and White, {Allan H.}",

year = "1988",

doi = "10.1071/CH9881925",

language = "English",

volume = "41",

pages = "1925--1934",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "12",

}

Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine. / Raston, Colin L.; Skelton, Brian W.; Whitaker, Claire R. et al.

In: Australian Journal of Chemistry, Vol. 41, No. 12, 1988, p. 1925-1934.

Research output: Contribution to journal › Article › peer-review

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T1 - Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - Whitaker, Claire R.

AU - White, Allan H.

PY - 1988

Y1 - 1988

N2 - Crystalline adducts of the lithium(I) halides, LiX (X = Cl, Br, I) with N, N, N′, N′-tetramethylethyl- enediamine (tmeda) have been synthesized and characterized by single-crystal X-ray studies. Both bromide and iodide form 1:1 adducts which are μ, μ′-dihalo-bridged binuclear species, [(tmeda)LiX1 unit solvated by chelating and bridging tmeda units.

AB - Crystalline adducts of the lithium(I) halides, LiX (X = Cl, Br, I) with N, N, N′, N′-tetramethylethyl- enediamine (tmeda) have been synthesized and characterized by single-crystal X-ray studies. Both bromide and iodide form 1:1 adducts which are μ, μ′-dihalo-bridged binuclear species, [(tmeda)LiX1 unit solvated by chelating and bridging tmeda units.

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DO - 10.1071/CH9881925

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JO - Australian Journal of Chemistry

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Lewis-Base Adducts of Main Group 1 Metal Compounds. IX Synthesis and Structural Characterization of Adducts of the Lithium(I) Halides with N, N, N′, N′-Tetramethylethylenediamine

Abstract

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