TY - JOUR
T1 - Lewis-base adducts of main group 1 metal compounds. V Diaquabis(quinoline)lithium(I) Bromide Bis(quinoline)
AU - Raston, Colin L.
AU - Skelton, Brian W.
AU - Whitaker, Claire R.
AU - White, Allan H.
PY - 1988
Y1 - 1988
N2 - The title compound, an artefact of recrystallization of lithium bromide from improperly dried quinoline, has been characterized by a single-crystal X-ray structure determination. Crystals are triclinic, P1, a 16.608(9), b 12.27(1), c 7.962(8)Å, α 101.98(8), β91.79(7), γ 92.27(6), Z 2; R was 0.058 for 2404 ‘observed’ reflections. The cation is the first to be structurally defined for a [Li(OH2)2 (N-base)2]+ system; Li-O are 1.92(2), 1.93(2) Å and Li-N 2.12(2), 2.14(2) Å.
AB - The title compound, an artefact of recrystallization of lithium bromide from improperly dried quinoline, has been characterized by a single-crystal X-ray structure determination. Crystals are triclinic, P1, a 16.608(9), b 12.27(1), c 7.962(8)Å, α 101.98(8), β91.79(7), γ 92.27(6), Z 2; R was 0.058 for 2404 ‘observed’ reflections. The cation is the first to be structurally defined for a [Li(OH2)2 (N-base)2]+ system; Li-O are 1.92(2), 1.93(2) Å and Li-N 2.12(2), 2.14(2) Å.
UR - http://www.scopus.com/inward/record.url?scp=84970616682&partnerID=8YFLogxK
U2 - 10.1071/CH9880409
DO - 10.1071/CH9880409
M3 - Article
AN - SCOPUS:84970616682
VL - 41
SP - 409
EP - 412
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 3
ER -