Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases

Colin L. Raston; Claire R. Whitaker; Allan H. White

doi:10.1071/CH9881917

Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases

Colin L. Raston, Claire R. Whitaker, Allan H. White

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Crystallization of lithium(I) nitrate from 2-methylpyridine and 3, 5-dimethylpyridine yields 1:2 and 1:3 adducts respectively, characterized by single-crystal X-ray structure determination. The 1:2 adduct is a linear polymeric species with the lithium atom four-coordinated by two monodentate ligands and two oxygen atoms of O, O′-bridging nitrate groups; there are two crystallographically independent polymeric strands in the structure. The 1:3 adduct is mononuclear, again with four-coordinate lithium. The three Li-N distances range from 2•05(2) to 2•08(2) Å, while Li-O is 1•98(2) Å.

Original language	English
Pages (from-to)	1917-1924
Number of pages	8
Journal	Australian Journal of Chemistry
Volume	41
Issue number	12
DOIs	https://doi.org/10.1071/CH9881917
Publication status	Published - 1988
Externally published	Yes

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title = "Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases",

abstract = "Crystallization of lithium(I) nitrate from 2-methylpyridine and 3, 5-dimethylpyridine yields 1:2 and 1:3 adducts respectively, characterized by single-crystal X-ray structure determination. The 1:2 adduct is a linear polymeric species with the lithium atom four-coordinated by two monodentate ligands and two oxygen atoms of O, O′-bridging nitrate groups; there are two crystallographically independent polymeric strands in the structure. The 1:3 adduct is mononuclear, again with four-coordinate lithium. The three Li-N distances range from 2•05(2) to 2•08(2) {\AA}, while Li-O is 1•98(2) {\AA}.",

author = "Raston, {Colin L.} and Whitaker, {Claire R.} and White, {Allan H.}",

year = "1988",

doi = "10.1071/CH9881917",

language = "English",

volume = "41",

pages = "1917--1924",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "12",

}

Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases. / Raston, Colin L.; Whitaker, Claire R.; White, Allan H.
In: Australian Journal of Chemistry, Vol. 41, No. 12, 1988, p. 1917-1924.

Research output: Contribution to journal › Article › peer-review

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T1 - Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases

AU - Raston, Colin L.

AU - Whitaker, Claire R.

AU - White, Allan H.

PY - 1988

Y1 - 1988

N2 - Crystallization of lithium(I) nitrate from 2-methylpyridine and 3, 5-dimethylpyridine yields 1:2 and 1:3 adducts respectively, characterized by single-crystal X-ray structure determination. The 1:2 adduct is a linear polymeric species with the lithium atom four-coordinated by two monodentate ligands and two oxygen atoms of O, O′-bridging nitrate groups; there are two crystallographically independent polymeric strands in the structure. The 1:3 adduct is mononuclear, again with four-coordinate lithium. The three Li-N distances range from 2•05(2) to 2•08(2) Å, while Li-O is 1•98(2) Å.

AB - Crystallization of lithium(I) nitrate from 2-methylpyridine and 3, 5-dimethylpyridine yields 1:2 and 1:3 adducts respectively, characterized by single-crystal X-ray structure determination. The 1:2 adduct is a linear polymeric species with the lithium atom four-coordinated by two monodentate ligands and two oxygen atoms of O, O′-bridging nitrate groups; there are two crystallographically independent polymeric strands in the structure. The 1:3 adduct is mononuclear, again with four-coordinate lithium. The three Li-N distances range from 2•05(2) to 2•08(2) Å, while Li-O is 1•98(2) Å.

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JO - Australian Journal of Chemistry

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Lewis-Base Adducts of Main Group 1 Metal Compounds. VIII Synthesis and Structural Characterization of 1:2 and 1:3 Adducts of Lithium Nitrate with Monodentate Nitrogen Bases

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