Lewis-base adducts of main group 1 metal compounds. XIII synthesis and structures of some pyridine base/lithium bromide and iodide adducts

Colin L. Raston, Ward T. Robinson, Brian W. Skelton, R. Claire Whitaker, Allan H. White

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The syntheses and single-crystal X-ray structure determinations of adducts of the lithium(I) halides with the following stoichiometries are reported: 1:3 lithium(I) bromide, iodide/pyridine, monomers; 1:2 lithium(I) bromide/quinoline and lithium(I) iodide/quinaldine, both as [L2LiX2LiL2] dimers; and 1:1 lithium(I) iodide/2, 4, 6-trimethylpyridine, ‘step’ tetramer.

Original languageEnglish
Pages (from-to)1163-1173
Number of pages11
JournalAustralian Journal of Chemistry
Volume43
Issue number7
DOIs
Publication statusPublished - 1990
Externally publishedYes

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