Lewis-base adducts of main group 1 metal compounds. XIII synthesis and structures of some pyridine base/lithium bromide and iodide adducts

Colin L. Raston; Ward T. Robinson; Brian W. Skelton; R. Claire Whitaker; Allan H. White

doi:10.1071/CH9901163

Lewis-base adducts of main group 1 metal compounds. XIII synthesis and structures of some pyridine base/lithium bromide and iodide adducts

Colin L. Raston, Ward T. Robinson, Brian W. Skelton, R. Claire Whitaker, Allan H. White

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The syntheses and single-crystal X-ray structure determinations of adducts of the lithium(I) halides with the following stoichiometries are reported: 1:3 lithium(I) bromide, iodide/pyridine, monomers; 1:2 lithium(I) bromide/quinoline and lithium(I) iodide/quinaldine, both as [L₂LiX₂LiL₂] dimers; and 1:1 lithium(I) iodide/2, 4, 6-trimethylpyridine, ‘step’ tetramer.

Original language	English
Pages (from-to)	1163-1173
Number of pages	11
Journal	Australian Journal of Chemistry
Volume	43
Issue number	7
DOIs	https://doi.org/10.1071/CH9901163
Publication status	Published - 1990
Externally published	Yes

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title = "Lewis-base adducts of main group 1 metal compounds. XIII synthesis and structures of some pyridine base/lithium bromide and iodide adducts",

abstract = "The syntheses and single-crystal X-ray structure determinations of adducts of the lithium(I) halides with the following stoichiometries are reported: 1:3 lithium(I) bromide, iodide/pyridine, monomers; 1:2 lithium(I) bromide/quinoline and lithium(I) iodide/quinaldine, both as [L2LiX2LiL2] dimers; and 1:1 lithium(I) iodide/2, 4, 6-trimethylpyridine, {\textquoteleft}step{\textquoteright} tetramer.",

author = "Raston, {Colin L.} and Robinson, {Ward T.} and Skelton, {Brian W.} and Whitaker, {R. Claire} and White, {Allan H.}",

year = "1990",

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language = "English",

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journal = "Australian Journal of Chemistry",

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Lewis-base adducts of main group 1 metal compounds. XIII synthesis and structures of some pyridine base/lithium bromide and iodide adducts. / Raston, Colin L.; Robinson, Ward T.; Skelton, Brian W.; Whitaker, R. Claire; White, Allan H.

In: Australian Journal of Chemistry, Vol. 43, No. 7, 1990, p. 1163-1173.

Research output: Contribution to journal › Article › peer-review

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AB - The syntheses and single-crystal X-ray structure determinations of adducts of the lithium(I) halides with the following stoichiometries are reported: 1:3 lithium(I) bromide, iodide/pyridine, monomers; 1:2 lithium(I) bromide/quinoline and lithium(I) iodide/quinaldine, both as [L2LiX2LiL2] dimers; and 1:1 lithium(I) iodide/2, 4, 6-trimethylpyridine, ‘step’ tetramer.

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