TY - JOUR
T1 - Lewis-base adducts of main group metal(i) compounds. XI
T2 - Di-μ-iodo-bis(N, N, N′, N″, N″ -pentamethyl-diethylenetriamine-N, N′, N″-sodium)
AU - Raston, Colin L.
AU - Whitaker, Claire R.
AU - White, Allan H.
PY - 1989
Y1 - 1989
N2 - The synthesis and structural characterization of the 1:1 adduct of sodium(I) iodide and N, N, N′, N″, N″-pentamethyldiethylenetriamine (pmdeta), a novel coordination complex of sodium(I), is recorded. Single-crystal X-ray structure determination shows the compound to be a μ,μ′-diiodo-bridged dimer, with the tridentate base making up the five-coordinate environment of sodium: [(pmdeta)NaI2Na(pmdeta)]. Crystals are triclinic, P1, a 10.113(2), b 9.470(2), c 8.793(4) Å, α 114.48(2), β 92.09(2), γ 96.65(1)°, Z=1 dimer; R was 0.037 for 1837 'observed' reflections.
AB - The synthesis and structural characterization of the 1:1 adduct of sodium(I) iodide and N, N, N′, N″, N″-pentamethyldiethylenetriamine (pmdeta), a novel coordination complex of sodium(I), is recorded. Single-crystal X-ray structure determination shows the compound to be a μ,μ′-diiodo-bridged dimer, with the tridentate base making up the five-coordinate environment of sodium: [(pmdeta)NaI2Na(pmdeta)]. Crystals are triclinic, P1, a 10.113(2), b 9.470(2), c 8.793(4) Å, α 114.48(2), β 92.09(2), γ 96.65(1)°, Z=1 dimer; R was 0.037 for 1837 'observed' reflections.
UR - http://www.scopus.com/inward/record.url?scp=84970582376&partnerID=8YFLogxK
U2 - 10.1071/CH9891393
DO - 10.1071/CH9891393
M3 - Article
AN - SCOPUS:84970582376
VL - 42
SP - 1393
EP - 1396
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 8
ER -