Local and electronic structure of FeS, CoS, NiS: Ultrasoft sulfur L 2,3 X-ray absorption spectra analysis

A. N. Kravtsova; I. E. Stekhin; A. V. Soldatov; M. E. Fleet; S. L. Harmer

doi:10.1016/j.elspec.2005.01.014

Local and electronic structure of FeS, CoS, NiS: Ultrasoft sulfur L _2,3 X-ray absorption spectra analysis

A. N. Kravtsova, I. E. Stekhin, A. V. Soldatov, M. E. Fleet, S. L. Harmer

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The ultrasoft S L_2,3 X-ray absorption near-edge structure (XANES) spectra of FeS, CoS and NiS having the NiAs-type crystal structure have been measured and theoretical analysis of the experimental data has been done on the basis of full multiple scattering theory. The distribution of local partial density of electronic states has been established. A special kind of hybridization between metal 3d and sulfur p states has been found: sulfur p states are "squeezed out" of the energy region of the maximum of metal d electronic states.

Original language	English
Pages (from-to)	525-527
Number of pages	3
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	144-147
DOIs	https://doi.org/10.1016/j.elspec.2005.01.014
Publication status	Published - Jun 2005
Externally published	Yes

Keywords

CoS
DOS
Electronic structure
FeS
NiS
XANES

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10.1016/j.elspec.2005.01.014Licence: In Copyright

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title = "Local and electronic structure of FeS, CoS, NiS: Ultrasoft sulfur L 2,3 X-ray absorption spectra analysis",

abstract = "The ultrasoft S L2,3 X-ray absorption near-edge structure (XANES) spectra of FeS, CoS and NiS having the NiAs-type crystal structure have been measured and theoretical analysis of the experimental data has been done on the basis of full multiple scattering theory. The distribution of local partial density of electronic states has been established. A special kind of hybridization between metal 3d and sulfur p states has been found: sulfur p states are {"}squeezed out{"} of the energy region of the maximum of metal d electronic states.",

keywords = "CoS, DOS, Electronic structure, FeS, NiS, XANES",

author = "Kravtsova, {A. N.} and Stekhin, {I. E.} and Soldatov, {A. V.} and Fleet, {M. E.} and Harmer, {S. L.}",

year = "2005",

month = jun,

doi = "10.1016/j.elspec.2005.01.014",

language = "English",

volume = "144-147",

pages = "525--527",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

}

TY - JOUR

T1 - Local and electronic structure of FeS, CoS, NiS

T2 - Ultrasoft sulfur L 2,3 X-ray absorption spectra analysis

AU - Kravtsova, A. N.

AU - Stekhin, I. E.

AU - Soldatov, A. V.

AU - Fleet, M. E.

AU - Harmer, S. L.

PY - 2005/6

Y1 - 2005/6

N2 - The ultrasoft S L2,3 X-ray absorption near-edge structure (XANES) spectra of FeS, CoS and NiS having the NiAs-type crystal structure have been measured and theoretical analysis of the experimental data has been done on the basis of full multiple scattering theory. The distribution of local partial density of electronic states has been established. A special kind of hybridization between metal 3d and sulfur p states has been found: sulfur p states are "squeezed out" of the energy region of the maximum of metal d electronic states.

AB - The ultrasoft S L2,3 X-ray absorption near-edge structure (XANES) spectra of FeS, CoS and NiS having the NiAs-type crystal structure have been measured and theoretical analysis of the experimental data has been done on the basis of full multiple scattering theory. The distribution of local partial density of electronic states has been established. A special kind of hybridization between metal 3d and sulfur p states has been found: sulfur p states are "squeezed out" of the energy region of the maximum of metal d electronic states.

KW - CoS

KW - DOS

KW - Electronic structure

KW - FeS

KW - NiS

KW - XANES

UR - http://www.scopus.com/inward/record.url?scp=17444400480&partnerID=8YFLogxK

U2 - 10.1016/j.elspec.2005.01.014

DO - 10.1016/j.elspec.2005.01.014

M3 - Article

AN - SCOPUS:17444400480

SN - 0368-2048

VL - 144-147

SP - 525

EP - 527

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

ER -

Local and electronic structure of FeS, CoS, NiS: Ultrasoft sulfur L _2,3 X-ray absorption spectra analysis

Abstract

Keywords

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