Low energy elastic electron scattering from CF3Br molecules

Leigh Hargreaves, Jessica Brunton, Todd Maddern, Michael Brunger

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    3 Citations (Scopus)

    Abstract

    CF3Br is a potentially valuable precursor molecule for generating beams of gas phase Br radicals suitable for electron collisions studies. However, the utility of CF3Br for this purpose depends critically on the availability of sound scattering cross sections to allow the contribution of the precursor to be isolated within the total scattering signal. To this end, here we present elastic differential cross section (DCS) measurements for CF3Br at incident energies between 15 and 50eV. Comparison of these DCSs to those from the only other available experimental study [Sunohara et al., J. Phys. B: At., Mol. Opt. Phys. 36, 1843 (2003)] and a Schwinger multichannel with pseudo potentials (SMCPPs) calculation [Bettega et al., J. Phys. B: At., Mol. Opt. Phys. 36, 1263 (2003)] shows generally a very good accord. Integral elastic and momentum transfer cross sections, derived from our DCSs, are also found to be in quite good agreement with the SMCPP results.

    Original languageEnglish
    Article number124310
    Pages (from-to)Article: 124310
    Number of pages5
    JournalJournal of Chemical Physics
    Volume142
    Issue number12
    DOIs
    Publication statusPublished - 2015

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