Magnesium anthracene: An alternative to magnesium in the high yield synthesis of Grignard reagents

Colin L. Raston; Geoffrey Salem

doi:10.1039/C39840001702

Magnesium anthracene: An alternative to magnesium in the high yield synthesis of Grignard reagents

Colin L. Raston, Geoffrey Salem

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

Benzylic type di-Grignard reagents (2)-(5) and the mono-Grignard reagent (6) have been prepared by treating the appropriate organic chloride, for (2)-(6), or bromide, for (3) and (4), with magnesium anthracene in tetrahydrofuran in yields of, respectively, 92-96%, and 60 and 84%.

Original language	English
Pages (from-to)	1702-1703
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39840001702
Publication status	Published - 15 Dec 1984
Externally published	Yes

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Raston, C. L., & Salem, G. (1984). Magnesium anthracene: An alternative to magnesium in the high yield synthesis of Grignard reagents. Journal of the Chemical Society, Chemical Communications, (24), 1702-1703. https://doi.org/10.1039/C39840001702

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abstract = "Benzylic type di-Grignard reagents (2)-(5) and the mono-Grignard reagent (6) have been prepared by treating the appropriate organic chloride, for (2)-(6), or bromide, for (3) and (4), with magnesium anthracene in tetrahydrofuran in yields of, respectively, 92-96%, and 60 and 84%.",

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